1330579-01-5Relevant articles and documents
Enantioselective conjugate addition of alkenylboronic acids to indole-appended enones
Lundy, Brian J.,Jansone-Popova, Santa,May, Jeremy A.
supporting information; experimental part, p. 4958 - 4961 (2011/11/29)
An enantioselective addition of alkenylboronic acids and alkynylboronic esters to unprotected indole-appended enones is reported. This transformation proceeds with high enantioselectivity and high product yields via the use of catalytic amounts of 3,3′-bis(pentafluorophenyl)-BINOL and Mg(Ot-Bu) 2. A range of α-branched indole derivatives are available from the transformation.