1330745-60-2Relevant academic research and scientific papers
Re(I)-Catalyzed Hydropropargylation of Silyl Enol Ethers Utilizing Dynamic Interconversion of Vinylidene-Alkenylmetal Intermediates via 1,5-Hydride Transfer
Iwasawa, Nobuharu,Watanabe, Shoya,Ario, Akane,Sogo, Hideyuki
, p. 7769 - 7772 (2018)
Re(I)-catalyzed hydropropargylation reaction of silyl enol ethers was realized utilizing dynamic interconversion of vinylidene-alkenylmetal intermediates, where alkenylmetals underwent 1,5-hydride transfer of the α-hydrogen to generate vinylidene intermediates. Furthermore, this process was found to be in an equilibrium.
Silver-mediated exo-selective tandem desilylative bromination/ oxycyclization of silyl-protected alkynes: Synthesis of 2-bromomethylene- tetrahydrofuran
Lee, Hyun-Ji,Lim, Chaemin,Hwang, Soonho,Jeong, Byeong-Seon,Kim, Sanghee
, p. 1943 - 1947 (2011/11/30)
Three in one: The exocyclic β-bromo enol ether is a synthetically useful functional moiety in the preparation of functionalized oxygen heterocycles. A new tandem method for the synthesis of this valuable moiety has been achieved by employing silyl-protect
