133160-49-3

Basic information

• Product Name: [Co(PPh₃)2(CO)2Cl]
• CAS NO: 133160-49-3
• Molecular Weight: 675.049
• Mol File: 133160-49-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Co(PPh₃)2(CO)2Cl](CAS DataBase Reference)
• NIST Chemistry Reference: [Co(PPh₃)2(CO)2Cl](133160-49-3)
• EPA Substance Registry System: [Co(PPh₃)2(CO)2Cl](133160-49-3)

Safety Data

• Hazardous Substances Data: 133160-49-3(Hazardous Substances Data)

Upstream product

• 101702-01-6 Cl^(1-)*Co⁽¹⁺⁾*P(C₆H₅)3=ClCo(P(C₆H₅)3) 
• 10025-87-3 trichlorophosphate 

Downstream Products

• 19178-87-1 {Co(CO)3(P(C₆H₅)3)2}⁽¹⁺⁾*ClO₄^(1-)={Co(CO)3(P(C₆H₅)3)2}ClO₄ 
• 101759-01-7 (C₆F₅)Co(CO)2(P(C₆H₅)3)2 
• 101759-02-8 {Co(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2}⁽¹⁺⁾*ClO₄^(1-)={Co(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2}ClO₄ 
• 22323-13-3 {Co(CO)(P(OCH₃)3)4}⁽¹⁺⁾*B(C₆H₅)4^(1-)={Co(CO)(P(OCH₃)3)4}B(C₆H₅)4 
• 58592-05-5 Co(CO)2(P(CH₃)(C₆H₅)2)3⁽¹⁺⁾*ClO₄^(1-)=[Co(CO)2(P(CH₃)(C₆H₅)2)3](ClO₄) 
• 1402436-06-9 C₃₈H₃₀Cl₃CoO₂P₂Sn 
• 1402436-14-9 C₆₂H₄₅CoO₂P₂Sn 
• 33570-17-1 sodium tricarbonyl(triphenylphosphino)cobaltate 
• 12078-25-0 dicarbonylcyclopentadienylcobalt 

Relevant articles and documents

CARBONYLCOBALT(I) COMPLEXES. THE CRYSTAL AND MOLECULAR STRUCTURE OF (Co(CO)(dppm)2)ClO4

New anionic carbonylcobalt(I) complexes (X2Co(CO)2(PPh3))(PR4) (X=Cl, PR4=PBzPh3 (I); X=Br, PR4=PEtPh3 (II)) have been prepared by reduction of the cobalt(II) halides with NaBH4 in the presence of PPh3 and the phosphonium salt PR4X.Cleavage of halide bridges in dimeric or polymeric (XCo(PPh3)2)n and (XCo(PPh3))n gives the neutral dicarbonyl derivatives XCo(CO)2(PPh3)2.Treatment of ClCo(CO)2(PPh3)2 with alkylating agents gives the known ?- and η-organocobalt(I) derivatives, and reactions with TlClO4 in the presence of various amounts of different mono- and bi-dentate phosphines give the cationic tricarbonyl (Co(CO)3(PPh3)2)(+), dicarbonyl (Co(CO)2(PMePh2)3)(+) and monocarbonyl (Co(CO)L4)(+) complexes (L4=4P(OMe)3, 2 dppe and 2 dppm).The dppm complex crystallizes in the monoclinic space group P21/c with a 17.895(6), b 10.751(2), c 24.687(4) angstroem, β 98.92(1) deg, and Dcalc 1.35 g cm-3 for Z=4.A final R value of 0.077 (Rw=0.061), based on 2656 observed reflections, was obtained.The cobalt atom exhibits a distored trigonal bipyramidal geometry.The perchlorate anion is severely disordered or freely rotating.