133170-89-5Relevant academic research and scientific papers
Kinetics of the reversible displacement of chloride by amines under the trans effect of phosphines, phosphites, and arsines
Gosling, Roy,Tobe, Martin L.
, p. 1235 - 1244 (2008/10/08)
The rate and equilibrium constants are reported for the reaction [Pt(L)Cl3] + am → trans-[Pt(L)(am)Cl2] + Cl (L = PMe3, PEt3, P-n-Bu3, PPh3, P(OMe)3, AsEt3; am is one of a series of amines and heterocyclic bases covering a wide range of basicity) in methanol at 30.0°C, μ = 0.50. The behavior patterns are discussed and compared with those of complexes where L is a sulfur donor ligand. The lability is strongly dependent upon the nature of the donor atom (P, As, or S) but far less sensitive to the nature of the substituents.
