1331748-60-7

Basic information

• Product Name: 2,2'-dimorpholino-1,1'-binaphthyl
• CAS NO: 1331748-60-7
• Molecular Weight: 424.543
• Mol File: 1331748-60-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2'-dimorpholino-1,1'-binaphthyl(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-dimorpholino-1,1'-binaphthyl(1331748-60-7)
• EPA Substance Registry System: 2,2'-dimorpholino-1,1'-binaphthyl(1331748-60-7)

Safety Data

• Hazardous Substances Data: 1331748-60-7(Hazardous Substances Data)

Upstream product

• 580-13-2 2-bromonaphthalene 
• 7508-21-6 N-(2-naphthyl)morpholine 
• 121-69-7 N,N-dimethyl-aniline 

Relevant articles and documents

Heterogeneous Rhodium-Catalyzed Aerobic Oxidative Dehydrogenative Cross-Coupling: Nonsymmetrical Biaryl Amines

The first heterogeneously catalyzed oxidative dehydrogenative cross-coupling of aryl amines is reported herein. 2-Naphthylamine analogues were reacted with various electron-rich arenes using a heterogeneous Rh/C catalyst under mild aerobic conditions, thus affording nonsymmetrical biaryl amines in excellent yields with high selectivities. This reaction provides a mild, operationally simple, and efficient approach for the synthesis of biaryls which are important to pharmaceutical and materials chemistry. A jab-cross move: A heterogeneously catalyzed oxidative dehydrogenative cross-coupling of aryl amines is reported. Aryl amines were treated with various arenes using a heterogeneous Rh/C catalyst under mild aerobic conditions to selectively afford cross-coupled products, and provides an efficient synthetic method for the preparation of nonsymmetrical biaryl amines by oxidative C-H activation.