1331843-55-0

Basic information

• Product Name: N,N'-dicyclohexyl-(1-amino)perylene-3,4,9,10-tetracarboxylic acid bisimide
• Synonyms: N,N'-dicyclohexyl-(1-amino)perylene-3,4,9,10-tetracarboxylic acid bisimide
• CAS NO: 1331843-55-0
• Molecular Weight: 569.66
• Mol File: 1331843-55-0.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: N,N'-dicyclohexyl-(1-amino)perylene-3,4,9,10-tetracarboxylic acid bisimide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-dicyclohexyl-(1-amino)perylene-3,4,9,10-tetracarboxylic acid bisimide(1331843-55-0)
• EPA Substance Registry System: N,N'-dicyclohexyl-(1-amino)perylene-3,4,9,10-tetracarboxylic acid bisimide(1331843-55-0)

Safety Data

• Hazardous Substances Data: 1331843-55-0(Hazardous Substances Data)

Upstream product

• 128-69-8 perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride 
• 41572-86-5 N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide 
• 108-91-8 cyclohexylamine 
• 1257079-45-0 2,9-dicyclohexyl-5-nitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone 

Relevant articles and documents

Synthesis, characterization, physical properties, and OLED application of single BN-fused perylene diimide

It is very challenging to introduce azaborine into an electrondeficient arene system because of unfavorable intramolecular electrophilic borylation reaction. In this report, we adopted a straightforward methodology to construct a large BN-embedded π-syste

Self-assembled nanorods of bay functionalized perylenediimide: Cu2+ based 'turn-on' response for INH, complementary NOR/OR and TRANSFER logic functions and fluorosolvatochromism

We designed and synthesized the mono bay functionalized perylenediimide (PDI) derivative PDI-DMEA which undergoes self-assembly to form a nanorod morphology. The diameter of these nanorods is in the range of 150-300 nm and the length extended up to the μm range. These nanorods on interaction with Cu2+ ions transformed into spherical aggregates having a diameter of 350-600 nm in accordance with DLS studies. In solution, PDI-DMEA shows a blue shift of the internal charge transfer (ICT) absorption band from 605 to 570 nm along with a hyperchromic effect at 570 nm, in the presence of 0.7 equivalents of Cu2+ ions. The addition of 2 equivalents of Cu2+ ions results in complete disappearance of the ICT band at 570 nm and appearance of a normal absorption band of PDI at 515 nm (a visual colour change from colourless to yellow). On the other hand PDI-DMEA shows a strong fluorescence 'turn-on' response at 537 and 573 nm on addition of higher equivalents of Cu2+ ions. Thus, PDI-DMEA represents several examples of molecular switches such as 'OFF-ON-OFF' and 'ON-OFF-ON' at 570/515 nm (Cu2+, absorbance), and 'OFF-ON' at 570 nm (Fe2+, absorbance) and 537 nm (Cu2+, fluorescence) and thus offers the possibility for developing NOR, OR, INH and TRANSFER logic and complimentary logic circuits. Moreover, PDI-DMEA and the PDI-DMEA-Cu2+ complex show fluorosolvatochromism which helps to develop a colour array for differentiating organic solvents. The detailed mechanism of interaction of Cu2+ and Fe2+ with PDI-DMEA, confocal laser scanning microscopic studies, dynamic light scattering, 1H NMR titration and reversibility are discussed.

1,6- and 1,7-Regioisomers of asymmetric and symmetric Perylene Bisimides: Synthesis, characterization and optical properties

The 1,6- and 1,7-regioisomers of dinitro- (1,6-A and 1,7-A) and diamino-substituted perylene bisimides (1,6-B and 1,7-B), and 1-Amino-6-nitro- and 1-Amino-7-nitroperylene bisimides (1,6-C and 1,7-C) were synthesized. The 1,6-A and 1,7-A regioisomers were