133188-94-0

Basic information

• Product Name: Benzene, (2-nonynylthio)-
• CAS NO: 133188-94-0
• Molecular Formula: C15H20S
• Molecular Weight: 232.39
• Mol File: 133188-94-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, (2-nonynylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-nonynylthio)-(133188-94-0)
• EPA Substance Registry System: Benzene, (2-nonynylthio)-(133188-94-0)

Safety Data

• Hazardous Substances Data: 133188-94-0(Hazardous Substances Data)

Upstream product

• 629-05-0 n-octyne 
• 51849-22-0 iodomethyl phenyl sulfide 
• 5921-73-3 2-nonyn-1-ol 
• 930-69-8 sodium thiophenolate 
• 58793-83-2 non-2-yn-1-yl methanesulfonate 
• 7205-91-6 phenylthiomethyl chloride 
• 38761-67-0 1-bromo-1-octyne 
• 81216-13-9 8-bromooct-1-yne 

Downstream Products

• 198982-63-7 3-chloro-1-nonenylthio benzene 
• 2463-53-8 non-2-enal 
• 194856-83-2 2-diethylamino-1-nonenyl phenyl sulfone 
• 194856-87-6 1-phenyl sulfonyl-2-nonanone 
• 113138-67-3 1-methoxy-2-nonynyl phenyl sulfide 
• 41103-67-7 1-(phenylsulfinyl)nonan-2-one 
• 111-80-8 methyl non-2-ynoate 
• 1846-70-4 non-2-ynoic acid 
• 194856-79-6 2-nonynyl phenyl sulfone 
• 194856-68-3 2-nonynyl phenyl sulfoxide 
• 198982-50-2 2-nonenylthio benzene 
• 153940-39-7 (1-Chloro-non-2-ynylsulfanyl)-benzene 

Relevant articles and documents

Synthesis of α-acetylenic aldehydes from 2-acetylenic phenyl sulfides

Monochlorination at the 1 position, with sulfuryl chloride, followed by hydrolysis converted 2-acetylenic phenyl sulfides into 2-acetylenic aldehydes.

Preparation of Functionalized Zinc and Copper Organometallics Containing Sulfur Functionalities at the Alpha or Gamma Position

α-Chloroalkyl phenyl sulfides 1 readily insert zinc in THF at 25 deg C (0.5-2 h), affording sulfur stabilized organozinc derivatives of type 2.The presence of a functional group such as an ester or a cyano group is tolerated in these organometallics.After a transmetallation to the corresponding copper reagent 3, they react with a wide range of electrophiles.Zinc and copper organometallics bearing a thiophenyl or a phenylsulfinyl group at the γ-position have also been prepared showing the generality of our approach.