133189-63-6Relevant academic research and scientific papers
Conjugatively stabilized bridgehead olefins: Formation and reaction of remarkably stable homoadamant-3-enes substituted with phenyl and methoxycarbonyl groups
Ohno, Masatomi,Itoh, Motohiro,Umeda, Masami,Furuta, Ryoji,Kondo, Kazumoto,Eguchi, Shoji
, p. 7075 - 7082 (1996)
Conjugatively stabilized double bonds were formed at the bridgehead of homoadamantane by way of the 1,2-carbon shift of adamantylcarbene (-carbenoid) intermediates generated from decomposition of the diazo precursors (1-adamantyl)diazophenylmethane (7) an
A new route to 3-labeled or 3-substituted 4-homoadamantanones
Takeuchi,Yoshida,Nishida,Kohama,Kitagawa
, p. 37 - 40 (2007/10/02)
The pinacol rearrangement of 3,4-dihydroxyhomoadamantanes containing carbon-13, deuterium, and alkyl, or an aryl subsituent at the C-4 position provides a new route to the title compounds.
