133192-39-9

Upstream product

• 132783-15-4 ((4R,5R)-4,5-Dimethyl-[1,3]dioxolan-2-ylidene)-(4-methoxy-phenyl)-amine 
• 1439-07-2 trans-Stilbene oxide 

Relevant academic research and scientific papers

Stereocontrolled Oxazolidinone Formation by the Addition of 4,5-Disubstituted Iminodioxolane to Oxirane via a Spiro Compound

4,5-Disubstituted 2-imino-1,3-dioxolanes readily add to oxiranes in the presence of AlCl3, furnishing 1,3-oxazolidin-2-ones in a stereospecific manner, where the configurations of oxiranes and iminodioxolanes are responsible for the configuration of products and the feasibility of the addition, respectively.A preliminary adduct, a spiro compound intermediate, is isolated, and its decomposition to oxazolidinone is demonstrated.