Journal of Organic Chemistry p. 2684 - 2688 (1991)
Update date:2022-07-30
Topics:
Baba, Akio
Seki, Kenji
Matsuda, Haruo
4,5-Disubstituted 2-imino-1,3-dioxolanes readily add to oxiranes in the presence of AlCl3, furnishing 1,3-oxazolidin-2-ones in a stereospecific manner, where the configurations of oxiranes and iminodioxolanes are responsible for the configuration of products and the feasibility of the addition, respectively.A preliminary adduct, a spiro compound intermediate, is isolated, and its decomposition to oxazolidinone is demonstrated.
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