133205-53-5

Upstream product

• 3282-30-2 pivaloyl chloride 
• 2687-12-9 cinnamyl chloride 
• 20971-19-1 (E)-2,2-dimethylhex-4-en-3-one 
• 507233-69-4 triphenyl bismuth ⁽²⁺⁾; dichloride 

Relevant academic research and scientific papers

Synthesis and reactivity of benzylic and allylic samarium compounds

Benzyl and allyl samarium species are prepared by reaction of benzylic or allylic chlorides with SmCp2. They present a wide scope of reactivity towards aldehydes, ketones and acid chlorides.

Synthesis and reactivity of allyl samarium complexes

Allyl chlorides react with SmCp2 to afford an allyl samarium intermediate, the η3-allyl structure of which has been tentatively assigned upon its reactivity with ketones. Synthesis of β,γ-unsaturated ketones have been also performed by reacting allyl samarium compounds with acid chlorides.