1332503-91-9

Upstream product

• 98-88-4 benzoyl chloride 
• 63-68-3 L-methionine 
• 1303536-70-0 (S)-N-[1-hydroxy-4-(methylthio)butan-2-yl]benzamide 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 1099751-78-6 (+)-(2S)-N-benzyl-1-(tert-butyldimethylsiloxy)but-3-en-2-amine 
• 1332503-90-8 (S,E)-4-[benzyl(1-tert-butyldimethylsilyloxybut-3-en-2-yl)-amino]-2-methylbut-2-enyl acetate 
• 952041-48-4 (2S,3S,4S)-1-benzyl-2-[(tert-butyldimethylsilyloxy)methyl]-3-(iodomethyl)-4-(prop-1-en-2-yl)pyrrolidine 
• 1332503-92-0 (S)-N-[1-(tert-butyldimethylsilyloxy)-4-(methylsulfinyl)butan-2-yl]benzamide 
• 1332503-93-1 (S)-N-[1-(tert-butyldimethylsilyloxy)but-3-en-2-yl]benzamide 

Relevant academic research and scientific papers

Synthesis of (-)-α-Kainic Acid via TMSCl-Promoted Pd-Catalyzed Zinc-ene Cyclization of an Allyl Acetate

A highly practical synthesis of enantiopure (-)-α-kainic acid is accomplished in 37% overall yield, using 13 linear steps and a minimum of chromatographic separations via an unprecedentedTMSClpromoted palladium-catalyzed zinc-ene cyclization of an allyl acetate. (Figure presented)