133269-62-2

Upstream product

• 133520-57-7 (4S,5R)-4-(hydroxymethyl)-2,2-dimethyl-5-phenyl-1,3-dioxolane 
• 145332-90-7 (2R,3S)-2-methanol-3-<2-((1-phenyl-1-methoxymethoxy)but-3-en)yloxy>-3,4,5,6-tetrahydro-2H-pyran 
• 145376-17-6 (1R,2R)-1-phenyl-but-3-ene-1,2-diol 
• 145376-18-7 (4R,5R)-2,2-dimethyl-4-phenyl-5-vinyl-1,3-dioxolane 

Downstream Products

• 5650-40-8 (S)-2-hydroxypropiophenone 
• 5650-40-8 (R)-2-hydroxy-1-phenylpropan-1-one 
• 579-07-7 1-Phenylpropane-1,2-dione 
• 40421-51-0 (1R,2R)-1-phenylpropane-1,2-diol 

Relevant academic research and scientific papers

Asymmetric Synthesis of Syn 1,2-Diols via the Reaction of Aldehydes with Chiral γ-(Tetrahydropyranyloxy)allylstannanes

Asymmetric synthesis of syn 1,2-diols 3 has been accomplished via the reaction of the chiral γ-alkoxy-substituted allylstannane 1 with aldehydes in the presence of AlCl3 or AlCl3*OEt2, followed by a five-step operation to remove the chiral auxiliary.