133271-07-5Relevant academic research and scientific papers
Stereoselective total synthesis of (+)-(6R,2′S)-cryptocaryalactone and (-)-(6S,2′S)-epi cryptocaryalactone via asymmetric acetate aldol reaction
Yadav,Bhunia, Dinesh C.,Ganganna
supporting information; experimental part, p. 2496 - 2499 (2012/06/16)
The total synthesis of (+)-(6R,2′S)-cryptocaryalactone and (-)-(6S,2′S)-epi cryptocaryalactone is reported based on asymmetric acetate aldol reaction. Still-Gennari reaction, Evans acetal intramolecular oxa-Michael reaction and lactonisation are the key s
Enantioselective Chiral Borane-Mediated Aldol Reactions of Silyl Ketene Acetals with Aldehydes. Novel Effect of the Trialkylsilyl Group of the Silyl Ketene Acetal on the Reaction Course
Kiyooka, Syun-ichi,Kaneko, Yuichi,Komura, Misako,Matsuo, Hidehito,Nakano, Masahito
, p. 2276 - 2278 (2007/10/02)
Highly enantioselective aldol reactions of silyl ketene acetals with a variety of aldehydes were achieved by using chiral boranes prepared from the sulfonamides of α-amino acids.
