1333081-63-2Relevant academic research and scientific papers
Synthesis, spectral and thermal studies of zinc(II) and mercury(II) complexes with bidentate Schiff-base ligand (234-MeO-Ba)2En: The crystal structure of Zn(234-MeO-Ba)2En)I2
Khalaji,Jalali Akerdi,Grivani,Stoeckli-Evans,Das
, p. 578 - 584 (2011)
New Symmetric bidentate Schiff-base ligands N,N′-bis(2,3,4- trimethoxybenzylidene)-1,2-di-aminoethane, (234-MeO-Ba)2En, and its corresponding zinc(II) and mercury(II) complexes, Zn((234-MeO-Ba) 2En)I2 (I), Hg((234-MeO-Ba)2En)Cl2 (II) have been synthesized and characterized by elemental analyses (CHN), FT-IR and 1H NMR spectroscopy. The thermal behaviors of complexes were study using thermogravimetry in order to evaluate their thermal stability and thermal decomposition pathways. The crystal structure of I was determined from single-crystal X-ray diffraction. The coordination polyhedron about the zinc(II) center in complex I is best described as a distorted tetrahedron.
