67175-92-2Relevant academic research and scientific papers
Synthesis, spectral and thermal studies of zinc(II) and mercury(II) complexes with bidentate Schiff-base ligand (234-MeO-Ba)2En: The crystal structure of Zn(234-MeO-Ba)2En)I2
Khalaji,Jalali Akerdi,Grivani,Stoeckli-Evans,Das
experimental part, p. 578 - 584 (2011/11/13)
New Symmetric bidentate Schiff-base ligands N,N′-bis(2,3,4- trimethoxybenzylidene)-1,2-di-aminoethane, (234-MeO-Ba)2En, and its corresponding zinc(II) and mercury(II) complexes, Zn((234-MeO-Ba) 2En)I2 (I), Hg((234-MeO-Ba)2En)Cl2 (II) have been synthesized and characterized by elemental analyses (CHN), FT-IR and 1H NMR spectroscopy. The thermal behaviors of complexes were study using thermogravimetry in order to evaluate their thermal stability and thermal decomposition pathways. The crystal structure of I was determined from single-crystal X-ray diffraction. The coordination polyhedron about the zinc(II) center in complex I is best described as a distorted tetrahedron.
Benzylic imidazolidinium, 3,4,5,6-tetrahydropyrimidinium and benzimidazolium salts: Applications in ruthenium-catalyzed allylic substitution reactions
Yasar, Sedat,Oezdemir, Ismail,Cetinkaya, Bekir,Renaud, Jean-Luc,Bruneau, Christian
scheme or table, p. 2142 - 2149 (2009/04/04)
Imidazolidinium, tetrahydropyrimidinium and benzimidazolium salts were prepared. Upon reaction with tBuOK, they generate carbene ligands, which were associated in situ to [RuCp*(MeCN)3]PF6 to produce ruthenium catalysts that are acti
