1333237-25-4

Upstream product

• 1333237-24-3 (R)-1-(benzyloxy)-8-(tert-butyldiphenylsilyloxy)-5,5-dichlorooct-2-yn-4-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 121671-76-9 5-(tert-butyldiphenylsilyloxy)pentan-1-ol 
• 131216-47-2 5-(tert-butyldiphenylsilyloxy)pentanal 
• 111-29-5 1 ,5-pentanediol 
• 1333237-23-2 5-(tert-butyldiphenylsilyloxy)-2,2-dichloropentanal 

Downstream Products

• 1333237-62-9 (1R,2R,3S,4R,5R,6S)-1-((4R,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-1,2,3,5,6-pentachloro-7-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)heptan-4-ol 
• 1333237-61-8 (3R,4S,5R,6S,Z)-1-((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-di-methyl-1,3-dioxan-4-yl)-3,5,6-trichloro-7-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)hept-1-en-4-ol 
• 1333237-59-4 (Z)-tert-butyl(4,4-dichloro-4-((4R,5S,6S)-5-chloro-6-((Z)-2-((2S,3S)-3-((1R,2S)-1,2-dichloro-3-((S)-2,2-di-methyl-1,3-dioxolan-4-yl)propyl)oxiran-2-yl)vinyl)-2,2-dimethyl-1,3-dioxan-4-yl)butoxy)diphenylsilane 
• 1333237-58-3 5-(((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)methylsulfonyl)-1-phenyl-1H-tetrazole 
• 1333237-57-2 5-(((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)methylthio)-1-phenyl-1H-tetrazole 
• 1333237-56-1 ((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)methanol 
• 1354770-37-8 C₄₀H₄₇Cl₃O₆Si 
• 1354770-15-2 C₄₀H₄₇Cl₃O₆Si 
• 1333237-35-6 ((2S,3R)-3-(3-((4R,5S,6S)-6-(benzyloxymethyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-3,3-dichloropropyl)oxiran-2-yl)methanol 
• 1333237-34-5 methyl (Z)--((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-6,6-dichlorohex-2-en-1-ol 
• 1333237-33-4 methyl (Z)--((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-6,6-dichlorohex-2-enoate 
• 1333237-32-3 4-((4R,5S,6S)-6-(benzyloxymethyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-4,4-dichlorobutanal 
• 1333237-31-2 4-((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-4,4-dichlorobutan-1-ol 
• 1333237-30-1 (4-((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-4,4-dichlorobutoxy)(tert-butyl)diphenylsilane 

Relevant academic research and scientific papers

Synthesis of undecachlorosulfolipid A: Re-evaluation of the nominal structure

Halo-giant: The title compound at the left in the scheme was constructed by the synthesis and coupling of two stereochemically challenging fragments. A comparison of the NMR data of the synthetic material and the natural product indicates that the configuration had been misassigned in the latter. PT=5-(1-phenyltetrazolyl).