1333237-32-3

Upstream product

• 1333237-24-3 (R)-1-(benzyloxy)-8-(tert-butyldiphenylsilyloxy)-5,5-dichlorooct-2-yn-4-ol 
• 1333237-25-4 (R,e)-1-(benzyloxy)-8-(tert-butyldiphenylsilyloxy)-5,5-dichlorooct-2-en-4-ol 
• 1333237-26-5 (R)-1-((2S,3S)-3-(benzyloxymethyl)oxiran-2-yl)-5-(tert-butyldiphenylsilyloxy)-2,2-dichloropentan-1-ol 
• 1333237-27-6 1-((2R,3S)-3-((benzyloxy)methyl)oxiran-2-yl)-5-((tert-butyldiphenylsilyl)oxy)-2,2-dichloropentan-1-one 
• 1333237-28-7 (2S,3S)-1-(benzyloxy)-8-(tert-butyldiphenylsilyloxy)-3,5,5-trichloro-2-hydroxyoctan-4-one 
• 1333237-29-8 (2S,3S,4R)-1-(benzyloxy)-8-((tert-butyldiphenylsilyl)oxy)-3,5,5-trichlorooctane-2,4-diol 
• 1333237-30-1 (4-((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-4,4-dichlorobutoxy)(tert-butyl)diphenylsilane 
• 1333237-31-2 4-((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-4,4-dichlorobutan-1-ol 
• 1333237-23-2 5-(tert-butyldiphenylsilyloxy)-2,2-dichloropentanal 
• 111-29-5 1 ,5-pentanediol 
• 131216-47-2 5-(tert-butyldiphenylsilyloxy)pentanal 
• 121671-76-9 5-(tert-butyldiphenylsilyloxy)pentan-1-ol 

Downstream Products

• 1333237-34-5 methyl (Z)--((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-6,6-dichlorohex-2-en-1-ol 
• 1333237-35-6 ((2S,3R)-3-(3-((4R,5S,6S)-6-(benzyloxymethyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-3,3-dichloropropyl)oxiran-2-yl)methanol 
• 1333237-33-4 methyl (Z)--((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-6,6-dichlorohex-2-enoate 

Relevant academic research and scientific papers

Stereochemical Revision, Total Synthesis, and Solution State Conformation of the Complex Chlorosulfolipid Mytilipin B

Chlorosulfolipids constitute a structurally intriguing and synthetically challenging class of marine natural products that are isolated from mussels and freshwater algae. The most complex structure from this family of compounds is currently represented by

Synthesis of undecachlorosulfolipid A: Re-evaluation of the nominal structure

Halo-giant: The title compound at the left in the scheme was constructed by the synthesis and coupling of two stereochemically challenging fragments. A comparison of the NMR data of the synthetic material and the natural product indicates that the configuration had been misassigned in the latter. PT=5-(1-phenyltetrazolyl).