1333237-59-4

Upstream product

• 1333237-24-3 (R)-1-(benzyloxy)-8-(tert-butyldiphenylsilyloxy)-5,5-dichlorooct-2-yn-4-ol 
• 1333237-25-4 (R,e)-1-(benzyloxy)-8-(tert-butyldiphenylsilyloxy)-5,5-dichlorooct-2-en-4-ol 
• 1333237-26-5 (R)-1-((2S,3S)-3-(benzyloxymethyl)oxiran-2-yl)-5-(tert-butyldiphenylsilyloxy)-2,2-dichloropentan-1-ol 
• 1333237-27-6 1-((2R,3S)-3-((benzyloxy)methyl)oxiran-2-yl)-5-((tert-butyldiphenylsilyl)oxy)-2,2-dichloropentan-1-one 
• 1333237-28-7 (2S,3S)-1-(benzyloxy)-8-(tert-butyldiphenylsilyloxy)-3,5,5-trichloro-2-hydroxyoctan-4-one 
• 1333237-29-8 (2S,3S,4R)-1-(benzyloxy)-8-((tert-butyldiphenylsilyl)oxy)-3,5,5-trichlorooctane-2,4-diol 
• 1333237-30-1 (4-((4R,5S,6S)-6-((benzyloxy)methyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-4,4-dichlorobutoxy)(tert-butyl)diphenylsilane 
• 1333237-56-1 ((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)methanol 
• 1333237-57-2 5-(((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)methylthio)-1-phenyl-1H-tetrazole 
• 1333237-60-7 C₁₁H₁₆Cl₂O₄ 
• 1333237-58-3 5-(((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)methylsulfonyl)-1-phenyl-1H-tetrazole 
• 1333236-45-5 (4R,5S,E)-4,5-dichloro-6-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)hex-2-en-1-ol 
• 1333237-61-8 (3R,4S,5R,6S,Z)-1-((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-di-methyl-1,3-dioxan-4-yl)-3,5,6-trichloro-7-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)hept-1-en-4-ol 
• 1333237-13-0 tert-butyl((4R,5S,e)-4,5-dichloro-6-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)hex-2-enyloxy)-dimethylsilane 

Downstream Products

• 1333237-61-8 (3R,4S,5R,6S,Z)-1-((4S,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-di-methyl-1,3-dioxan-4-yl)-3,5,6-trichloro-7-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)hept-1-en-4-ol 
• 1333237-62-9 (1R,2R,3S,4R,5R,6S)-1-((4R,5S,6R)-6-(4-(tert-butyldiphenylsilyloxy)-1,1-dichlorobutyl)-5-chloro-2,2-dimethyl-1,3-dioxan-4-yl)-1,2,3,5,6-pentachloro-7-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)heptan-4-ol 

Relevant academic research and scientific papers

Synthesis of undecachlorosulfolipid A: Re-evaluation of the nominal structure

Halo-giant: The title compound at the left in the scheme was constructed by the synthesis and coupling of two stereochemically challenging fragments. A comparison of the NMR data of the synthetic material and the natural product indicates that the configuration had been misassigned in the latter. PT=5-(1-phenyltetrazolyl).