1333318-85-6

Basic information

• Product Name: C₁₉H₃₆O₃Si
• Synonyms: C₁₉H₃₆O₃Si
• CAS NO: 1333318-85-6
• Molecular Weight: 340.579
• Mol File: 1333318-85-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₉H₃₆O₃Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₃₆O₃Si(1333318-85-6)
• EPA Substance Registry System: C₁₉H₃₆O₃Si(1333318-85-6)

Safety Data

• Hazardous Substances Data: 1333318-85-6(Hazardous Substances Data)

Upstream product

• 1333318-97-0 C₁₆H₃₂OSi 
• 166022-33-9 ((R)-(-)-2,2-dimethyl-6-methylene-1-cyclohexyl)methanol 
• 292638-85-8 acrylic acid methyl ester 
• 407-47-6 2,2,2-trifluoroethyl acrylate 
• 1333318-98-1 C₁₆H₃₂O₂Si 
• 1333318-86-7 C₁₆H₃₂O₂Si 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Relevant articles and documents

A unified strategy for the synthesis of (-)-maoecrystal Z, (-)-trichorabdal A, and (-)-longikaurin E

Herein we describe in full our investigations that led to the completion of the first total syntheses of (-)-maoecrystal Z, (-)-trichorabdal A, and (-)-longikaurin E. The unified strategy employs a TiIII-mediated reductive epoxide coupling to rapidly prepare a key spirolactone. Highly diastereoselective SmII-mediated reductive cyclizations and a Pd II-mediated oxidative cyclization enable the construction of three architecturally distinct ent-kauranoid frameworks from this common intermediate.