133334-07-3Relevant academic research and scientific papers
DINUCLEAR TITANOCENE CHALCOGENIDES AS SULFUR AND SELENIUM TRANSFER REAGENTS IN RING SYNTHESIS
Steudel, Ralf,Jensen, Detlef,Papavassiliou, Maria
, p. 349 - 354 (2007/10/02)
The dinuclear titanocene complexes Cp4Ti2S6, Cp4Ti2S4 and Cp4Ti2Se4 have been reacted with SCl2, S2Cl2, and Se2Cl2, respectively.The reaction products are rings of type Sn (n=6...20) and six-, seven- and eight-membered rings of type SexSy, respectively, which have been characterized by HPLC, Raman and Se-NMR spectroscopy, as well as X-ray diffraction on single crystals.
