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Sulfur chloride
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10025-67-9 Usage

Purification Methods

It isa pungent, irritating golden yellow liquid. When impure its colour is orange to red due to SCl2 formed. It fumes in moist air and liberates HCl, SO2 and H2S in the presence of H2O. Distil it and collect the fraction boiling above 137o at atmospheric pressure. Fractionate this fraction over sulfur at ca 12mm using a ground glass apparatus (b 29-30o). Alternatively purify it by distillation below 60o from a mixture containing sulfur (2%) and activated charcoal (1%), under reduced pressure (e.g. 50mm). It is soluble in EtOH, *C6H6, Et2O, CS2 and CCl4. Store it in a closed container in the dark in a refrigerator. [Fehér in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 371 1963.] HARMFUL VAPOURS.

Uses

Intermediate and chlorinating agent in manufacture of organics, sulfur dyes, insecticides, and synthetic rubber.

Preparation

Sulfur chloride is prepared as an orange liquid by passing chlorine gas through molten sulfur. If excess chlorine is passed and in the presence of a trace FeCl3 or iodine as catalyst, an equilibrium mixture of about 85% dichloride, SCl2 , and 15% S2Cl2 is obtained. The dichloride dissociates to sulfur chloride: 2SCl2 ? S2Cl2 + Cl2 Sulfur chloride is separated by fractional distillation.

Uses

Intermediate and chlorinating agent in the manufacture of organic chemicals, sulfur dyes, insecticides, synthetic rubbers; in cold vulcanization of rubber; as polymerization catalyst for vegetable oils; for hardening soft woods.

Physical Properties

Yellowish red oily liquid; pungent penetrating odor; fumes in air; refractive index 1.670 at 20°C; dipole moment 1.60; dielectric constant 4.9 at 22°C; reacts with water; soluble in ethanol, benzene, ether, chloroform, and carbon tetrachloride: dissolves sulfur at ambient temperature (67 g/100 g sulfur chloride).

Shipping

UN1828 Sulfur chlorides, Hazard class: 8; Labels: 8-Corrosive material, Potential Inhalation Hazard (Special Provision 5)

Waste Disposal

Wearing protective equipment, spray carefully onto sodium ash/slaked lime mixture. Then spray with water, dilute, neutralize and flush to drain.

Uses

Sulfur chloride (S2Cl2) is combustible and will react when in contact with water. It is used to produce carbon tetrachloride, to purify sugar juices, to extract gold from its ore, in insecticides, and as a poisonous gas for military/combat purposes.

Uses

Sulfur chloride is a solvent for sulfur and a chlorinating agent. Other applications are vulcanizing rubber; an intermediate in making sulfur dyes, synthetic rubber, thionyl chloride, and several other compounds; pesticide formulations; hardening soft woods; and extracting gold.

Safety Profile

Poison by ingestion and inhalation. A fuming, corrosive liquid very irritating to shin, eyes, and mucous membranes. It decomposes on contact with water to form the highly irritating hydrogen chloride, thiosulfuric acid, and sulfur. Its toxic effects are irritating to the upper respiratory tract, although the results of intoxication are usually transitory in nature. However, if hydrolysis is not complete in the upper respiratory tract, injury to the broncholes and alveoli can result. A fire hazard when in contact with organic matter, P203, Na2O2, water, Cr(OCl)2. Combustible when exposed to heat or flame. Will react with water or steam to produce heat and toxic and corrosive fumes. Can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of Cland SOX.

Potential Exposure

Sulfur chloride finds use as a chlorinating agent, catalyst, and as an intermediate in the manufacture of organic chemicals; carbon tetrachloride; sulfur dyes; insecticides, synthetic rubber; and pharmaceuticals. Exposure may also occur during the extraction of gold, purification of sugar juice; finishing and dyeing textiles; processing vegetable oils; hardening wood; and vulcanization of rubber. Has been used as a military poison.

Chemical Properties

Amber to yellowish-red, oily, fuming liquid; penetrating odor. Soluble in alcohol, ether, benzene, carbon disulfide, and amyl acetate; decomposes on contact withwater. Combustible.

Chemical Properties

Sulfur chloride is a fuming, oily liquid with a yellowish-red to amber color and a suffocating odor. It has an added hazard since it oxidizes and hydrolyzes to sulfur dioxide and hydrogen chloride.

Hazard

Reacts violently withwater in closed vessel. Toxic by inhalation and ingestion, strong irritant to tissue, eyes, skin, and upper respiratory tract.

Incompatibilities

Decomposes violently in water, forming hydrochloric acid, sulfur dioxide; sulfur, sulfite, thiosulfate, and hydrogen sulfide. Reacts with oxidizers, strong bases; peroxides, phosphorus oxides; organics, antimony, antimony sulfide; arsenic sulfide; mercury oxide; tin, alkenes, terpenes, unsaturated glycerides; chromyl chloride; methyl sulfoxide; dimethylformamide, acetone, and other compounds; causing fire and explosion hazard. Corrosive to many metals in presence of water. Attacks some plastics, rubber and coatings.

Toxicity

Sulfur chloride is toxic and a lachrymator. The vapors can cause irritation of the eyes, nose, and respiratory tract.

Health Hazard

Sulfur monochloride is an irritant of the eyes, mucous membranes, and skin. On contact with water, it decomposes to form hydrogen chloride and sulfur dioxide; because this occurs rapidly, it acts primarily as an upper respiratory irritant and does not ordinarily reach the lungs. However, exposure to high concentrations may cause pulmonary edema.

Definition

A red fuming liquid with a strong smell. It is prepared by passing chlorine over molten sulfur and is used to harden rubber.
InChI:InChI=1/2ClH.H2S/h2*1H;1H2/q;;+2/p-2

10025-67-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Disulfur Dichloride

1.2 Other means of identification

Product number -
Other names chlorosulfanyl thiohypochlorite

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10025-67-9 SDS

10025-67-9Synthetic route

sulfur
10544-50-0

sulfur

molybdenum pentachloride

molybdenum pentachloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

Mo(5+)*3Cl(1-)*S2(2-)=*MoCl3(S2)

Mo(5+)*3Cl(1-)*S2(2-)=*MoCl3(S2)

Conditions
ConditionsYield
In further solvent(s) (under exclusion of moisture); refluxing in S2Cl2 at 160°C for 5 h; ppt. filtered, washed (CHCl2);A n/a
B 96%
tetrachloromethane
56-23-5

tetrachloromethane

sulfur
10544-50-0

sulfur

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

carbon disulfide
75-15-0

carbon disulfide

Conditions
ConditionsYield
byproducts: S(x)Cl2; (N2), bomb reed, heated at 250°C for 24 h; cooled in liquid air in vac., distd.;A 95%
B n/a
byproducts: S(x)Cl2; (N2), bomb reed, heated at 250°C for 15 h; cooled in liquid air in vac., distd.;A 86%
B n/a
byproducts: S(x)Cl2; (N2), bomb reed, heated at 210°C for 8 d; cooled in liquid air in vac., distd.;A 70%
B n/a
barite

barite

chlorine
7782-50-5

chlorine

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

barium(II) chloride

barium(II) chloride

Conditions
ConditionsYield
With chaircoal with activated chaircoal at 500 °C;A n/a
B 90%
With chaircoal with activated chaircoal at 500 °C;A n/a
B 90%
In melt reduction to BaS in molten BaCl2; blowing chlorine into the melt;
With coal or coke or hydrocarbons at higher temp.;
In melt reduction to BaS in molten BaCl2; blowing chlorine into the melt;
sulfur
10544-50-0

sulfur

chloroform
67-66-3

chloroform

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

disulfur dichloride
10025-67-9

disulfur dichloride

C

carbon disulfide
75-15-0

carbon disulfide

Conditions
ConditionsYield
(N2), bomb reed, heated at 205°C for 60 h; cooled in liquid air in vac. for a week, distd.; Raman spectr.;A n/a
B 80%
C n/a
sulfur
7704-34-9

sulfur

diselenium dichloride
10025-68-0

diselenium dichloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur selenium dichloride
1087399-32-3

sulfur selenium dichloride

C

sulfur dichloride
10545-99-0

sulfur dichloride

D

selenium tetrachloride
10026-03-6

selenium tetrachloride

Conditions
ConditionsYield
In neat (no solvent) heating of equimolar amount in closed tube to 200°C for 6 h;; fractional distillation;;A n/a
B 30%
C n/a
D n/a
In neat (no solvent) heating of equimolar amount in closed tube to 200°C for 6 h;; fractional distillation;;A n/a
B 30%
C n/a
D n/a
In neat (no solvent) heating of equimolar amount in closed tube to 100, 150, 200 or 250°C for 6 h;; fractional distillation;;
In neat (no solvent) heating of equimolar amount in closed tube to 100, 150, 200 or 250°C for 6 h;; fractional distillation;;
arsenic trisulfide

arsenic trisulfide

chlorine
7782-50-5

chlorine

disulfur dichloride
10025-67-9

disulfur dichloride

Conditions
ConditionsYield
In not given room temp.;;
dimethylsulfide
75-18-3

dimethylsulfide

chlorine
7782-50-5

chlorine

disulfur dichloride
10025-67-9

disulfur dichloride

Conditions
ConditionsYield
In not given
In not given
sulfur
7704-34-9

sulfur

nitrosylchloride
2696-92-6

nitrosylchloride

disulfur dichloride
10025-67-9

disulfur dichloride

Conditions
ConditionsYield
In further solvent(s) introduction of NOCl into soln. of S in S2Cl2;;
sulfur
7704-34-9

sulfur

nitrosylchloride
2696-92-6

nitrosylchloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

Conditions
ConditionsYield
In neat (no solvent) introduction of NOCl, 100°C;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sulfur
7704-34-9

sulfur

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur dioxide
7446-09-5

sulfur dioxide

Conditions
ConditionsYield
In neat (no solvent) decompn. under explosion;;
arsenic

arsenic

Iodine monochloride
7790-99-0

Iodine monochloride

cadmium(II) sulphide

cadmium(II) sulphide

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur
7704-34-9

sulfur

C

cadmium(II) iodide

cadmium(II) iodide

carbon disulfide
75-15-0

carbon disulfide

iodine trichloride
865-44-1

iodine trichloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

tetrachloromethane
56-23-5

tetrachloromethane

C

sulfur tetrachloride * iodine trichloride

sulfur tetrachloride * iodine trichloride

Conditions
ConditionsYield
In neat (no solvent) room temp.;;
carbon disulfide
75-15-0

carbon disulfide

chlorine
7782-50-5

chlorine

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

tetrachloromethane
56-23-5

tetrachloromethane

C

thiophosgene
463-71-8

thiophosgene

Conditions
ConditionsYield
In gas passing through glowing tube of porcelaine;;
carbon disulfide
75-15-0

carbon disulfide

chlorine
7782-50-5

chlorine

disulfur dichloride
10025-67-9

disulfur dichloride

Conditions
ConditionsYield
In neat (no solvent) room temp.;;
In not given0%
carbon disulfide
75-15-0

carbon disulfide

chlorine
7782-50-5

chlorine

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

tetrachloromethane
56-23-5

tetrachloromethane

Conditions
ConditionsYield
In neat (no solvent) room temp.; presence of iodine, SbCl5, MoCl5;;
iron sulfide

iron sulfide

chlorine
7782-50-5

chlorine

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

iron(II) chloride

iron(II) chloride

Conditions
ConditionsYield
In neat (no solvent) fast reaction of FeS and Cl2 with evolution of heat;;
thionyl chloride
7719-09-7

thionyl chloride

cadmium(II) sulphide

cadmium(II) sulphide

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur dioxide
7446-09-5

sulfur dioxide

C

cadmium(II) chloride
10108-64-2

cadmium(II) chloride

Conditions
ConditionsYield
In neat (no solvent) reaction of CdS with SOCl2 in a sealed tube at 200 °C;;
In neat (no solvent) reaction of CdS with SOCl2 in a sealed tube at 200 °C;;
potassium chloride

potassium chloride

disulfur dichloride
10025-67-9

disulfur dichloride

Conditions
ConditionsYield
With sulfur
With S
With sulfur
sodium chloride
7647-14-5

sodium chloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sodium sulfide

sodium sulfide

Conditions
ConditionsYield
With S In melt reaction during melting;;
With sulfur In melt reaction during melting;;
copper(I) sulfide
22205-45-4

copper(I) sulfide

sodium chloride
7647-14-5

sodium chloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

copper oxychloride

copper oxychloride

C

copper(II) sulfate
7758-99-8

copper(II) sulfate

D

copper dichloride

copper dichloride

Conditions
ConditionsYield
With oxygen byproducts: Na2SO4, SO2; information about the react. eqs. in detail and about dependence on temp.;
With oxygen byproducts: Na2SO4, SO2; information about the react. eqs. in detail and about dependence on temp.;
mercury sulfide

mercury sulfide

chlorine
7782-50-5

chlorine

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur dichloride
10545-99-0

sulfur dichloride

C

mercury dichloride

mercury dichloride

Conditions
ConditionsYield
below 200°C;; almost pure;;A n/a
B n/a
C >99
thionyl chloride
7719-09-7

thionyl chloride

mercury(II) oxide

mercury(II) oxide

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfuryl dichloride
7791-25-5

sulfuryl dichloride

C

mercury dichloride

mercury dichloride

Conditions
ConditionsYield
In neat (no solvent) excess of SOCl2;;
In neat (no solvent) excess of SOCl2;;
carnallite

carnallite

magnesium sulfide

magnesium sulfide

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur
7704-34-9

sulfur

C

magnesium
7439-95-4

magnesium

Conditions
ConditionsYield
Electrolysis;
magnesium sulfide

magnesium sulfide

magnesium chloride
7786-30-3

magnesium chloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur
7704-34-9

sulfur

C

magnesium
7439-95-4

magnesium

Conditions
ConditionsYield
Electrolysis;
lead(II) sulfide

lead(II) sulfide

chlorine
7782-50-5

chlorine

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

lead(II) chloride

lead(II) chloride

Conditions
ConditionsYield
In neat (no solvent) slow reaction of PbS and Cl2 without evolution of heat;;
thionyl chloride
7719-09-7

thionyl chloride

zinc sulfide

zinc sulfide

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur dioxide
7446-09-5

sulfur dioxide

C

zinc(II) chloride
7646-85-7

zinc(II) chloride

Conditions
ConditionsYield
In neat (no solvent) reaction last several days at 150 - 200 °C;;
zinc sulfide

zinc sulfide

copper dichloride

copper dichloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

copper(I) sulfide
22205-45-4

copper(I) sulfide

C

zinc(II) chloride
7646-85-7

zinc(II) chloride

Conditions
ConditionsYield
below 150°C;
below 150°C;
thionyl chloride
7719-09-7

thionyl chloride

phosphorus

phosphorus

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur dioxide
7446-09-5

sulfur dioxide

C

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

Conditions
ConditionsYield
In neat (no solvent) excess SOCl2; 125°C;;
In neat (no solvent) excess SOCl2; 125°C;;
disulfur dichloride
10025-67-9

disulfur dichloride

bismuth
7440-69-9

bismuth

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
heating Bi with S2Cl2 at 138.6°C, 10 hours;;100%
addition of S2Cl2 to Bi;;
addition of S2Cl2 to Bi;;
disulfur dichloride
10025-67-9

disulfur dichloride

[(C5H5)2Ti(S4C6H10)]
88510-23-0

[(C5H5)2Ti(S4C6H10)]

bis(cyclopentadienyl)titanium dichloride
1271-19-8

bis(cyclopentadienyl)titanium dichloride

Conditions
ConditionsYield
In carbon disulfide byproducts: C6H10S6; air atm.; equimolar ratio, stirring, pptn.; filtn. (SiO2);100%
disulfur dichloride
10025-67-9

disulfur dichloride

barium sulfate

barium sulfate

barium(II) chloride

barium(II) chloride

Conditions
ConditionsYield
With chlorine heating in a stream of S2Cl2 and chlorine;100%
With chlorine heating in a stream of S2Cl2 and chlorine;100%
disulfur dichloride
10025-67-9

disulfur dichloride

dimethyl amine
124-40-3

dimethyl amine

N,N'-dithiobis-methanamine
928-05-2

N,N'-dithiobis-methanamine

Conditions
ConditionsYield
In diethyl ether at -78 - 20℃; for 1.23333h;99%
With triethylamine In dichloromethane at -20 - 20℃; for 1h;73%
disulfur dichloride
10025-67-9

disulfur dichloride

sulfur
7704-34-9

sulfur

molybdenum
7439-98-7

molybdenum

molybdenum sulphide chloride

molybdenum sulphide chloride

Conditions
ConditionsYield
In neat (no solvent) sealed quartz ampoule (vac.), heating (150°C, 2 h; then 420°C, 40 h); drying (vac., 150°C); elem. anal.;98%
disulfur dichloride
10025-67-9

disulfur dichloride

molybdenum

molybdenum

sulfur
7704-34-9

sulfur

(92)Mo3S7(4+)*4Cl(1-)=(92)Mo3S7Cl4

(92)Mo3S7(4+)*4Cl(1-)=(92)Mo3S7Cl4

Conditions
ConditionsYield
In neat (no solvent) sealed quartz ampoule (vac.), heating (150°C, 2 h; then 420°C, 40 h); drying (vac., 150°C);98%
disulfur dichloride
10025-67-9

disulfur dichloride

molybdenum

molybdenum

sulfur
7704-34-9

sulfur

(100)Mo3S7(4+)*4Cl(1-)=(100)Mo3S7Cl4

(100)Mo3S7(4+)*4Cl(1-)=(100)Mo3S7Cl4

Conditions
ConditionsYield
In neat (no solvent) sealed quartz ampoule (vac.), heating (150°C, 2 h; then 420°C, 40 h); drying (vac., 150°C);98%
disulfur dichloride
10025-67-9

disulfur dichloride

molybdenum hexacarbonyl
13939-06-5, 199620-15-0

molybdenum hexacarbonyl

2Mo(4+)*6Cl(1-)*S2(2-)*CH2Cl2=Mo2Cl6S2*CH2Cl2

2Mo(4+)*6Cl(1-)*S2(2-)*CH2Cl2=Mo2Cl6S2*CH2Cl2

Conditions
ConditionsYield
With CH2Cl2 In dichloromethane byproducts: CO; Irradiation (UV/VIS); standard Schlenk or glove-box techniques, addn. of S2Cl2 to a suspension of Mo(CO)6 in CH2Cl2, heating to reflux, irradiation (150 W W filament bulb), CO evolution, cooling to room temp. after 3.5 h; pptn., filtration, washing (CH2Cl2, Et2O), drying in vac., elem. anal.;98%
disulfur dichloride
10025-67-9

disulfur dichloride

molybdenum hexacarbonyl
13939-06-5, 199620-15-0

molybdenum hexacarbonyl

molybdenum(V) sulphide trichloride

molybdenum(V) sulphide trichloride

Conditions
ConditionsYield
In chloroform byproducts: CO, S; 65°C, 0.5 h;97%
In tetrachloromethane byproducts: CO, S; 80°C, 0.5 h;85%
disulfur dichloride
10025-67-9

disulfur dichloride

N-2-pyridylimidoyl-2-pyridylamidine
1605332-69-1

N-2-pyridylimidoyl-2-pyridylamidine

C12H9N5S2(2+)*2Cl(1-)

C12H9N5S2(2+)*2Cl(1-)

Conditions
ConditionsYield
In acetonitrile for 16h; Inert atmosphere; Reflux;96%
disulfur dichloride
10025-67-9

disulfur dichloride

Pentafluorobenzene
363-72-4

Pentafluorobenzene

pentafluorophenyl sulfide
1043-50-1

pentafluorophenyl sulfide

Conditions
ConditionsYield
With antimony pentafluoride 60°C, 1 h;94%
With SbF5 60°C, 1 h;94%
disulfur dichloride
10025-67-9

disulfur dichloride

bis{N-(N''-morpholinyl-thiocarbonyl)benzamidinato}-nitrido-technetium(V)chloride

bis{N-(N''-morpholinyl-thiocarbonyl)benzamidinato}-nitrido-technetium(V)chloride

dichloro{N-(N''-morpholinyl-thiocarbonyl)benzamidinato}(thionitrosyl)-technetium(II)

dichloro{N-(N''-morpholinyl-thiocarbonyl)benzamidinato}(thionitrosyl)-technetium(II)

Conditions
ConditionsYield
In dichloromethane addn. of S2Cl2 to a soln. of the Tc-complex; stirring (room temp., 2 h).;; filtn., washing (ether), elem. anal.;;94%
disulfur dichloride
10025-67-9

disulfur dichloride

arsenic(III) trioxide

arsenic(III) trioxide

arsenic trichloride
7784-34-1

arsenic trichloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: SO2; heating of dry As2O3 to 95 to 100°C under reflux; addition of S2Cl2 in portions that temp. arise to 120 to 125°C;; distillation; 99% AsCl3;;93%
In neat (no solvent) room temp.;;
In neat (no solvent) byproducts: SO2, S; at 120°C;;
disulfur dichloride
10025-67-9

disulfur dichloride

sulfur
7704-34-9

sulfur

rhenium(VII) oxide

rhenium(VII) oxide

[Re3(μ3-S)(μ-S2)3Cl6]Cl

[Re3(μ3-S)(μ-S2)3Cl6]Cl

Conditions
ConditionsYield
In neat (no solvent)93%
disulfur dichloride
10025-67-9

disulfur dichloride

TcN(et2dtc)2
77933-43-8

TcN(et2dtc)2

dichlorobis(diethyldithiocarbamato)thionitrosyltechnetium(III)

dichlorobis(diethyldithiocarbamato)thionitrosyltechnetium(III)

Conditions
ConditionsYield
In dichloromethane S2Cl2 was added to soln. of Tc-complex in CH2Cl2, vol. was reduced, silica-gel column was used, eluted with CH2Cl2 and ethyl acetate/CH2Cl2; collected, recrystd. from ethyl acetate/CH2Cl2; elem. anal.;92%
disulfur dichloride
10025-67-9

disulfur dichloride

tetrasulfur tetranitride
28950-34-7

tetrasulfur tetranitride

thiotrithiazyl chloride
857244-78-1

thiotrithiazyl chloride

Conditions
ConditionsYield
In tetrachloromethane addn. of 6 fold excess S2Cl2 to S4Cl4 (in CCl4); heating with exclusion of moisture and air; pptn. on boiling; detailed description of apparatus and handling given;; washing (CCl4/N2 atm.); drying (vac.);;90%
In tetrachloromethane boiling for two hours;;
In tetrachloromethane according H. G. Heal, Adv. Inorg. Chem. Radiochim. 15 (1972) 375; boiling CCl4; crystn. on slowly cooling; XRD; DSC; TGA; DTA;
disulfur dichloride
10025-67-9

disulfur dichloride

bis(acetylacetonato)-3-formyl-acetylacetonatochromium(III)

bis(acetylacetonato)-3-formyl-acetylacetonatochromium(III)

Cr(S2(C(COCH3)2)2)(CH3COC(CHO)COCH3)

Cr(S2(C(COCH3)2)2)(CH3COC(CHO)COCH3)

Conditions
ConditionsYield
With sodium carbonate In dichloromethane under Ar; to a mixt. of the Cr complex and Na2CO3 in CH2Cl2 was added S2Cl2 in CH2Cl2, stirred for 2 d at 0°C; filtered, solvent was removed under reduced pressure, fractionated withEt2O; elem. anal.;90%
disulfur dichloride
10025-67-9

disulfur dichloride

ammonium hexafluorophosphate

ammonium hexafluorophosphate

[TcN(Cl)(C12H8N2)2](1+)*Cl(1-)*H2O = [TcN(Cl)(C12H8N2)2]Cl*H2O

[TcN(Cl)(C12H8N2)2](1+)*Cl(1-)*H2O = [TcN(Cl)(C12H8N2)2]Cl*H2O

[Tc(NS)Cl(C12H8N2)2](1+)*PF6(1-)*H2O = [Tc(NS)Cl(C12H8N2)2]PF6*H2O

[Tc(NS)Cl(C12H8N2)2](1+)*PF6(1-)*H2O = [Tc(NS)Cl(C12H8N2)2]PF6*H2O

Conditions
ConditionsYield
In chloroform refluxed (2 h); cooled; filtered; washed (CHCl3, Et2O); dissolved in water, filtered, NH4PF6 added to induce pptn.; elem. anal.;90%
disulfur dichloride
10025-67-9

disulfur dichloride

1-butanethiol
109-79-5

1-butanethiol

dibutyl tetrasulfide
5943-36-2

dibutyl tetrasulfide

Conditions
ConditionsYield
With triethylamine In dichloromethane at -20 - 20℃; for 1h;90%
disulfur dichloride
10025-67-9

disulfur dichloride

selenium
7782-49-2

selenium

osmium(VIII) oxide
20816-12-0

osmium(VIII) oxide

Os2S6Se2Cl8

Os2S6Se2Cl8

Conditions
ConditionsYield
In further solvent(s) byproducts: SO2; Oso4 added to 22% soln. of Se in S2Cl2, heated at 60-80°C until SO2 ceased to evolve, sealed, heated at 100°C for 40 h; ppt. septd., filtered under inert atm., washed (S2Cl2, CS2, CCl4), elem.anal.;90%
disulfur dichloride
10025-67-9

disulfur dichloride

sulfur
7704-34-9

sulfur

tungsten
7440-33-7

tungsten

tungsten(VI) sulfide tetrachloride
25127-53-1

tungsten(VI) sulfide tetrachloride

Conditions
ConditionsYield
In neat (no solvent) heating (2E-4 Torr, 425°C, 48 h), slow cooling;89%
disulfur dichloride
10025-67-9

disulfur dichloride

lithium perfluoro isopropylideneamide
31340-36-0

lithium perfluoro isopropylideneamide

bis(hexafluoroisopropylidene amino) disulfane
38005-16-2

bis(hexafluoroisopropylidene amino) disulfane

Conditions
ConditionsYield
25°C 8 h,;89%
25°C 8 h,;89%
disulfur dichloride
10025-67-9

disulfur dichloride

ReCl2N(n-propyldiphenylphosphine)2
25398-89-4

ReCl2N(n-propyldiphenylphosphine)2

trichlorobis(n-propyldiphenylphosphine)(thionitrosyl)rhenium
57894-34-5

trichlorobis(n-propyldiphenylphosphine)(thionitrosyl)rhenium

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; addn. of 0.5 equiv. S2Cl2 to Re-complex, stirring (1.5 h); evapn. (1E-2 Torr), crystn. (acetone); elem. anal.;89%
disulfur dichloride
10025-67-9

disulfur dichloride

bromochloronitridotris(diethylphenylphosphine)rhenium(V)

bromochloronitridotris(diethylphenylphosphine)rhenium(V)

bromochlorotris(diethylphenylphosphine)(thionitrosyl)rhenium
57902-90-6

bromochlorotris(diethylphenylphosphine)(thionitrosyl)rhenium

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; addn. of 0.5 equiv. S2Cl2 to Re-complex, stirring (room temp., 0.5 h); evapn. (1E-2 Torr), recrystn. (1,2-dichloroethane/pentane); elem. anal.;87%
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