1333402-29-1

Basic information

• Product Name: methyl 2-[(diphenylmethylene)amino]-3-(4-methylphenylsulfonamide)-3-(p-chlorophenyl)propanoate
• Synonyms: methyl 2-[(diphenylmethylene)amino]-3-(4-methylphenylsulfonamide)-3-(p-chlorophenyl)propanoate
• CAS NO: 1333402-29-1
• Molecular Weight: 547.074
• Mol File: 1333402-29-1.mol

Chemical Properties

• CAS DataBase Reference: methyl 2-[(diphenylmethylene)amino]-3-(4-methylphenylsulfonamide)-3-(p-chlorophenyl)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-[(diphenylmethylene)amino]-3-(4-methylphenylsulfonamide)-3-(p-chlorophenyl)propanoate(1333402-29-1)
• EPA Substance Registry System: methyl 2-[(diphenylmethylene)amino]-3-(4-methylphenylsulfonamide)-3-(p-chlorophenyl)propanoate(1333402-29-1)

Safety Data

• Hazardous Substances Data: 1333402-29-1(Hazardous Substances Data)

Upstream product

• 3157-65-1 N-(p-chlorobenzylidene)-p-toluenesulfonamide 
• 81167-39-7 methyl N-(diphenylmethylene)glycinate 

Relevant articles and documents

Ag/ThioClickFerrophos-catalyzed enantioselective mannich reaction and amination of glycine schiff base

The AgOAc/ThioClickFerrophos complex catalyzed the asymmetric Mannich reaction of glycine Schiff base with N-tosylimines effectively to give a mixture of syn and anti adducts (syn/anti = 60/40-70/30) at high yields with high enantioselectivities (up to 98% ee). The complex also catalyzed the asymmetric amination of glycine Schiff base with di-tert-butyl azodicarboxylate with high enantioselectivity.

Synthesis of α,β-diamino acid derivatives via asymmetric Mannich reactions of glycine imino esters catalyzed by a chiral phosphoramidite·silver complex Dedicated to the memory of Prof. Ekkehard Winterfeldt

AgOTf·phosphoramidite complexes efficiently catalyze the enantioselective Mannich-type reaction between benzophenone-imine glycine methyl ester and N-tosyl aldimines in the absence of a base. The corresponding syn-adducts, which are the direct precursors of α,β-diamino acids, are obtained with moderate to good syn-diastereoselectivities (up to 9:1) and high enantioselectivities (up to 99% ee).