1333475-20-9

Upstream product

• 608101-55-9 1-(2,2-diphenylvinylidene)-2,2-diphenylcyclopropane 
• 22219-36-9 1,1-bis(4-chlorophenyl)-2,2-dibromocyclopropane 
• 22125-54-8 1,1-dibromo-2,2-bis(4-fluorophenyl)cyclopropane 
• 70671-90-8 1,1-dibromo-2,2-bis(4-methylphenyl)cyclopropane 
• 17343-74-7 1,1-dibromo-2,2-diphenylcyclopropane 
• 73914-66-6 (ethene-1,1-diyl-2,2-d₂)dibenzene 
• 119-61-9 benzophenone 
• 1021301-95-0 C₂₉H₂₀Cl₂ 
• 110-91-8 morpholine 
• 1333475-22-1 C₂₉H₂₀⁽²⁾H₂ 

Relevant academic research and scientific papers

Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with secondary amines under an oxygen atmosphere

A Midas touch! Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with a variety of secondary amines proceeded smoothly in toluene or 1,1,2,2-tetrachloroethane (TCE) to give the corresponding amides in moderate to good yields under oxygen atmosphere (see scheme; DCE=1,2-dichloroethane). The scope and limitations as well as the plausible mechanisms have been discussed.