22219-36-9

Upstream product

• 593-94-2 dibromoiodomethane 
• 2642-81-1 1,1-bis(p-chlorophenyl)ethene 
• 90-98-2 4,4'-Dichlorobenzophenone 
• 557-95-9 bromodiiodomethane 
• 75-25-2 Bromoform 

Downstream Products

• 22125-44-6 1-Brom-2,2-bis-(p-chlorphenyl)-cyclopropan 
• 331676-33-6 1-bis-(4-chlorophenyl)vinylidene-2,2,3,3-tetramethylcyclopropane 
• 92426-91-0 4,4'-(propa-1,2-diene-1,1-diyl)bis(chlorobenzene) 
• 919341-26-7 C₂₅H₂₀Cl₂ 
• 1201909-59-2 1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-(4-chlorophenyl)vinyl)-4-chlorobenzene 
• 1210959-97-9 4-(2-(2,2-bis(4-chlorophenyl)vinylidene)-1-phenylcyclopropyl)butan-1-ol 
• 1313396-59-6 C₂₇H₂₃BrCl₂O 
• 1313396-68-7 C₂₇H₂₃Cl₂FO 
• 3439-04-1 4,4'-(prop-1-ene-1,1-diyl)bis(chlorobenzene) 
• 1361143-74-9 C₃₉H₃₂Cl₂Se₂ 
• 73914-66-6 (ethene-1,1-diyl-2,2-d₂)dibenzene 
• 1333475-20-9 C₂₀H₁₉⁽²⁾H₂NO₂ 
• 1333475-22-1 C₂₉H₂₀⁽²⁾H₂ 
• 119-61-9 benzophenone 

Relevant academic research and scientific papers

Synthesis of Quinolines via the Metal-free Visible-Light-Mediated Radical Azidation of Cyclopropenes

We report the synthesis of quinolines using cyclopropenes and an azidobenziodazolone (ABZ) hypervalent iodine reagent as an azide radical source under visible-light irradiation. Multisubstituted quinoline products were obtained in 34-81% yield. The reaction was most efficient for 3-trifluoromethylcyclopropenes, affording valuable 4-trifluoromethylquinolines. The transformation probably proceeds through the cyclization of an iminyl radical formed by the addition of the azide radical on the cyclopropene double bond, followed by ring-opening and fragmentation.

Photoredox-Catalyzed α-Aminoalkylcarboxylation of Allenes with CO2

The photoredox-catalyzed α-aminoalkylcarboxylation of aryl allenes with CO2 and N,N-dimethylanilines is reported for the first time (26 examples, up to 96% yield). In the case of electron-deficient allenes, good regioselectivity was observed (up to 94:6), exclusively generating kinetic products over thermodynamic products. This protocol is a novel synthetic method for highly functionalized β,γ-unsaturated γ-aminobutyric esters.

Regioselective Diboron-Mediated Semireduction of Terminal Allenes

A method for the regioselective reduction of the terminal double bond of 1,1-disubstituted allenes has been developed. In the presence of a palladium catalyst, tetrahydroxydiboron and stoichiometric water, allene semireduction proceeds in high yield to afford Z-alkenes selectively.

Rhodium-catalyzed polymerization of 3,3-diarylcyclopropenes involving a 1,4-rhodium migration

A new mode of metal-catalyzed polymerization reaction has been developed by exploiting the ability of 1,4-rhodium migration of an organorhodium(I) species. Specifically, it has been demonstrated that 3,3-diarylcyclopropenes undergo polymerization through

Reactions of vinylidenecyclopropanes with diphenyl diselenide in the presence of AIBN and thermally-induced further transformations

In conclusion, we have developed a novel tandem reaction of VDCPs 1 with PhSeSePh to give the corresponding bicyclo[3.1.0]hexane derivatives 4 in good yields in the presence of AIBN, which could undergo a thermal-induced radical 1,4-hydrogen shift through

An efficient method for the synthesis of alkylidenecyclobutanones by gold-catalyzed oxidative ring enlargement of vinylidenecyclopropanes

Rings of gold: Vinylidenecyclopropanes can undergo efficient oxidative ring enlargements under mild conditions to give the corresponding alkylidenecyclobutanone derivatives in good yields (see scheme). A plausible mechanism for this transformation has bee

Halogenation reagents initiating ring opening of vinylidenecyclopropanes: Easy access to halogenated tetrahydropyrans

A novel synthetic protocol that uses halogenation reagents (NBS, NIS and selectfluor) to initiate intramolecular ring-opening reactions of diarylvinylidenecyclopropanes (VDCPs) connected to alcohol-bearing chains has been developed. The approach provides

Lewis acid promoted reactions of ethenetricarboxylates with allenes: Synthesis of indenes and γ-lactones via conjugate addition/cyclization reaction

(Figure presented) Indenes are important core structures in organic chemistry. Few simple arylallenes have been used to construct indene skeletons by Friedel-Crafts reaction. Lewis acid catalyzed reaction of ethenetricarboxylates 1 and arylallenes has been examined in this study. The reaction of arylallenes and ethenetricarboxylate triesters with SnCl4 gave indene derivatives efficiently, via a conjugate addition/Friedel-Crafts cyclization reaction. On the other hand, the reactions of 1,1-diethyl 2-hydrogen ethenetricarboxylate and arylallenes or alkylallenes with SnCl4 at -78 °C or room temperature and subsequent treatment with Et3N gave γ-lactones. The reactions of triethyl ethenetricarboxylate and 1,1-dialkylallenes with SnCl4 at room temperature also gave γ-lactones.

Rhodium(I)-catalyzed intramolecular ene reaction of vinylidenecyclopropanes and alkenes for the formation of bicyclo[5.1.0]octylenes

"Chemical Equation Presented" An efficient catalytic system for the intramolecular ene reaction of allene and alkene of diarylvinylidenecyclopropanes has been established. The reaction was achieved by using [RhCl(CO)2]2 as the cataly

Au/Ag-catalyzed intramolecular ring-opening of vinylidene-cyclopropanes (VDCPs): An easy access to functional tetrahydropyrans

Chemical Equation Presentation An intramolecular ring-opening of vinylidenecyclopropanes (VDCPs) tethered with alcohol chains has been established. A serles of transition metal catalysts and their combinations have been screened under mild conditions, and