13336-54-4

Basic information

• Product Name: O-allyl phenyl-H-phosphinate
• Synonyms: O-allyl phenyl-H-phosphinate
• CAS NO: 13336-54-4
• Molecular Weight: 182.159
• Mol File: 13336-54-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: O-allyl phenyl-H-phosphinate(CAS DataBase Reference)
• NIST Chemistry Reference: O-allyl phenyl-H-phosphinate(13336-54-4)
• EPA Substance Registry System: O-allyl phenyl-H-phosphinate(13336-54-4)

Safety Data

• Hazardous Substances Data: 13336-54-4(Hazardous Substances Data)

Upstream product

• 1779-48-2 phenylphosphinic acid 
• 107-18-6 allyl alcohol 
• 2937-50-0 Allyl chloroformate 
• 1067-43-2 tetraallyloxysilane 

Downstream Products

• 1207552-72-4 allyl (1-hydroxy-2-methylprop-2-enyl)phenylphosphinate 
• 1207552-73-5 allyl (1-hydroxy-1-methylprop-2-enyl)phenylphosphinate 
• 1207552-71-3 allyl (1-hydroxybut-2-enyl)phenylphosphinate 
• 16324-18-8 2-phenyl-1,2λ⁵-oxaphospholane-2-thione 
• 104284-00-6 phenyl-thiophosphonigsaeure-O-allylester 

Relevant articles and documents

Convenient synthesis of allenylphosphoryl compounds: Via Cu-catalysed couplings of P(O)H compounds with propargyl acetates

A novel Cu-catalysed substitution reaction of propargyl acetates with P(O)H compounds is developed to afford allenylphosphoryl compounds via C-P bond coupling in high yields under mild conditions. A plausible mechanism involving the nucleophilic interception of the Cu-allenylidene intermediates is proposed.

Oxaphospholene and oxaphosphinene heterocycles via RCM using unsymmetrical phosphonates or functional phosphinates

New phosphorus heterocycles were synthesized using RCM reaction. They were prepared from unsymmetrical or polyfunctional insaturated precursor in 50 to 87% yields solving the problem of possible competitive side reactions. In parallel hydroxyphosphinate scaffolds represent a versatile starting material and could be of great interest for the synthesis of phosphosugar libraries.

Hewitt reaction revisited

A range of alkyl phenylphosphonites are prepared from the reaction of phenylphosphinic acid with the corresponding alkyl chloroformates. A mechanism for this reaction is proposed.