13336-55-5

Upstream product

• 14684-31-2 methyl hypophosphite 
• 624-31-7 4-tolyl iodide 
• 67-56-1 methanol 
• 13829-65-7 1-(4-methylphenyl)-3-methyl-2,5-dihydro-1H-phosphole 1-oxide 

Relevant academic research and scientific papers

Synthesis of H-phosphinates by the UV light - Mediated fragmentation- related phosphorylation using simple P-heterocycles

Photolysis of aryl-substituted 2,5-dihydrophosphole oxides (5a-e and 8) in the presence of methanol afforded methyl aryl-H-phosphinates (2a-e) in good yields. In the case of 1-ethyl-, cyclohexyl-, or ethoxy-2,5-dihydrophosphole oxides, the reaction was mu

Palladium catalyzed preparation of monoaryl and diarylphosphinates from methyl phosphinate

A simple and effective preparation of methyl esters of monoarylphosphinic acids has been developed, which involves palladium catalyzed coupling of aryl iodides with methyl phosphinate in the presence of tertiary amines or propylene oxide (1,2-epoxypropane