133374-51-3Relevant academic research and scientific papers
Ionic liquids as a convenient recyclable medium for the generation of transient carbonyl ylides: Syntheses of oxa and dioxa-bridged polycyclic systems
Muthusamy, Sengodagounder,Gnanaprakasam, Boopathy
, p. 1309 - 1315 (2007/10/03)
The tandem cyclization-cycloaddition reactions of α-diazo ketones in the presence of rhodium(II) acetate, rhodium(II) octanoate or copper(II) acetyl acetonate as catalyst were performed in different imidazole based ionic liquids as solvent. A successful g
Tandem Cyclization-Cycloaddition Reaction of Rhodium Carbenoids. Studies Dealing with the Geometric Requirements of Dipole Formation
Padwa, Albert,Chinn, Richard L.,Hornbuckle, Susan F.,Zhang, Zhijia J.
, p. 3271 - 3278 (2007/10/02)
The carbenoid intermediate derived by the treatment of several 1-diazabutadienediones with rhodium(II) acetate undergoes ready transannular cyclization onto the neighboring keto group to give five-membered ring carbonyl ylides.The dipole derived from ethy
CYCLIC CARBONYL YLIDE FORMATION FROM THE RHODIUM (II) ACETATE CATALYZED REACTION OF 1-DIAZOALKANEDIONES
Padwa, Albert,Chinn, Richard L.,Hornblucke, Susan F.,Zhi, Lin
, p. 301 - 304 (2007/10/02)
Treatment of 1-diazoalkanediones with rhodium (II) acetate results in cyclization of the intermediate rhodium carbenoid to give a cyclic carbonyl ylide which readily undergoes bimolecular dipolar cycloaddition with various dipolarophiles.
