133377-27-2Relevant academic research and scientific papers
Indirect electrochemical oxidation of aryl alkyl ketones mediated by NaI-NaOH system: Facile and effective way to α-hydroxyketals
Elinson, Michail N.,Feducovich, Sergey K.,Dorofeev, Alexander S.,Vereshchagin, Anatolii N.,Nikishin, Gennady I.
, p. 9999 - 10003 (2007/10/03)
Indirect electrochemical oxidation of aryl alkyl ketones in methanol in an undivided cell in the presence of sodium iodide-sodium hydroxide leads to the corresponding α-hydroxyketals in 75-85% substance yield (70-75% current yield). (C) 2000 Elsevier Scie
Electrochemical oxidation of ketones in methanol in the presence of alkali metal bromides
Nikishin, Gennady I.,Elinson, Michail N.,Makhova, Irina V.
, p. 895 - 905 (2007/10/02)
Electrochemical oxidation of methyl ketones in methanoi in the presence of alkali metal bromides affords methyl carboxylates. Benzyl alkyl ketones are transformed under similar conditions into methyl 3-phenylalkanoates, while ketones lacking σ-benzyl or σ-methyl group are oxidized into σ-hydroxyketals.
