133384-09-5

Basic information

• Product Name: 1-<α-(Dibenzylamino)benzyl>benzotriazole
• Synonyms: 1-<α-(Dibenzylamino)benzyl>benzotriazole
• CAS NO: 133384-09-5
• Molecular Weight: 404.514
• Mol File: 133384-09-5.mol

Chemical Properties

• CAS DataBase Reference: 1-<α-(Dibenzylamino)benzyl>benzotriazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-<α-(Dibenzylamino)benzyl>benzotriazole(133384-09-5)
• EPA Substance Registry System: 1-<α-(Dibenzylamino)benzyl>benzotriazole(133384-09-5)

Safety Data

• Hazardous Substances Data: 133384-09-5(Hazardous Substances Data)

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 100-52-7 benzaldehyde 
• 103-49-1 dibenzylamine 

Downstream Products

• 105541-15-9 tetra-N-benzyl-bibenzyl-α,α'-diyldiamine 
• 1256484-49-7 N,N-dibenzyl-2,3-dimethyl-1-phenylbut-2-en-1-amine 
• 1256484-48-6 (Z)-N,N-dibenzyl-2-methyl-1-phenylbut-2-en-1-amine 
• 1254833-32-3 1-(N,N-dibenzylamino)-1-phenyl-3-methylbut-2-ene 
• 1256484-56-6 N,N-dibenzyl-1-cyclopropyl-1-phenylmethanamine 

Relevant articles and documents

Aminoalkylations of esters, sulfones, sulfoxides, alkylated pyridines, and nitriles with in situ generated iminium ions

N-(α-Aminoalkyl)benzotriazoles, prepared from a variety of aldehydes and secondary amines, react with diverse ester enolates, sulfones, a sulfoxide, alkylated pyridines, and nitriles to provide novel access to β-amino carboxylic esters (55-80% yield), β-aminoalkyl sulfones (42-88% yield), β-aminoalkyl sulfoxides (20-32% yield), α- and γ-(β- aminoalkyl)pyridines (69-90% yield), and β-aminoalkyl cyanides (10-97% yield), respectively. Georg Thieme Verlag Stuttgart.

Forming All-Carbon Quaternary Stereocenters by Organocatalytic Aminomethylation: Concise Access to β2,2-Amino Acids

The asymmetric synthesis of β2,2-amino acids remains a formidable challenge in organic synthesis. Here a novel organocatalytic enantioselective aminomethylation of ketenes with stable and readily available N,O-acetals is reported, providing β2,2-amino esters bearing an all-carbon quaternary stereogenic center in high enantiomeric ratios with a catalytic amount of chiral phosphoric acid. Typically, this transformation probably proceeds through an asymmetric counter-anion-directed catalysis. As a result, a concise, practical, and atom-economic protocol toward rapidly access to β2,2-amino acids has been developed.

Classical benzotriazole-mediated α-aminoalkylations of alkynes: Synthesis and characterization of alk-2-yn-1-amines as amphiphilic materials

Reactions of readily available and stable benzotriazolemethanamines 1a-1, obtained from aldehydes and secondary amines (Scheme 2), gave the expected alk-2-yn-1-amines 3a-t (Scheme 3). The amphiphilic character of the synthesized products was responsible f

EPR studies on the Sml2-promoted coupling of N-(N′,N′-dialkylaminoalkyl)benzotriazoles

(formula presented) Radicals generated in the Sml2-promoted coupling of N-(N′,N′-dialkylaminoalkyl)benzotriazoles 1 have been detected using the EPR spintrapping technique. Single electron transfer (SET) between 1 and Sml2 is discuss