1334032-96-0Relevant articles and documents
Separate deprotonation reactions converge mechanistically for a new cyclization of benzyl 1-Alkynyl sulfones
Hossain, M. Selim,Schwan, Adrian L.
, p. 5330 - 5333 (2011/12/01)
A heretofore unknown LDA-induced conversion of benzyl 1-alkynyl sulfones to 1H-2-benzothiopyran-S,S-dioxides is demonstrated. A benzyl carbanion, accessible by two means, is thought to cyclize by temporary disruption of aromaticity. Key intermediates are