1334298-55-3

Basic information

• Product Name: 3a-fluoro-5-mesityl-8-methyl-1-tosyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole
• Synonyms: 3a-fluoro-5-mesityl-8-methyl-1-tosyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole
• CAS NO: 1334298-55-3
• Molecular Weight: 464.604
• Mol File: 1334298-55-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3a-fluoro-5-mesityl-8-methyl-1-tosyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole(CAS DataBase Reference)
• NIST Chemistry Reference: 3a-fluoro-5-mesityl-8-methyl-1-tosyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole(1334298-55-3)
• EPA Substance Registry System: 3a-fluoro-5-mesityl-8-methyl-1-tosyl-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole(1334298-55-3)

Safety Data

• Hazardous Substances Data: 1334298-55-3(Hazardous Substances Data)

Upstream product

• 117235-22-0 methyl 2-(5-bromo-1H-indole-3-yl)acetate 
• 1334298-69-9 methyl 2-(5-bromo-1-methyl-1H-indol-3-yl)acetate 
• 1334298-71-3 methyl 2-(5-mesityl-1-methyl-1H-indol-3-yl)acetate 
• 1334298-77-9 2-(5-mesityl-1-methyl-1H-indol-3-yl)-N-tosylacetamide 
• 1334298-39-3 N-(2-(5-mesityl-1-methyl-1H-indol-3-yl)ethyl)-4-methylbenzenesulfonamide 
• 40432-84-6 (5-bromo-1H-indol-3-yl)-acetic acid 

Relevant articles and documents

Enantioselective Fluorocyclizations Mediated by Amino-Acid-Derived Phthalazine

Novel amino-acid-derived phthalazine reagents have been designed and synthesized for the enantioselective fluorocyclizations of prochiral indoles. The scope of reaction is evidenced by 28 examples of fluorinated furoindole and pyrroloindole heterocycles b

Organocatalyzed enantioselective fluorocyclizations

Enantioenriched fluorinated heterocycles can be prepared through fluorocyclizations of prochiral indoles (see scheme; Ts=tosyl, Bn=benzyl, Boc=tert-butoxycarbonyl). More than twenty examples for this cascade fluorination-cyclization, which is catalyzed by cinchona alkaloids and employs N-fluorobenzenesulfonimide as the electrophilic fluorine source have been explored, and an unprecedented catalytic asymmetric difluorocyclization has also been identified.