1334447-07-2

Basic information

• Product Name: (E)-dimethyl 2,5-dibenzylhex-2-enedioate
• Synonyms: (E)-dimethyl 2,5-dibenzylhex-2-enedioate
• CAS NO: 1334447-07-2
• Molecular Weight: 352.43
• Mol File: 1334447-07-2.mol

Chemical Properties

• CAS DataBase Reference: (E)-dimethyl 2,5-dibenzylhex-2-enedioate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-dimethyl 2,5-dibenzylhex-2-enedioate(1334447-07-2)
• EPA Substance Registry System: (E)-dimethyl 2,5-dibenzylhex-2-enedioate(1334447-07-2)

Safety Data

• Hazardous Substances Data: 1334447-07-2(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 3666-82-8 2-benzyl-3-oxo-butyric acid methyl ester 
• 3070-71-1 methyl 2-benzylacrylate 

Relevant articles and documents

N-heterocyclic carbene catalyzed umpolung of Michael acceptors for intermolecular reactions

leahciM! The N-heterocyclic carbene catalyzed umpolung of Michael acceptors proceeds through the formation of a deoxy-Breslow intermediate (see scheme; EWG=electron-withdrawing group). This nucleophilic species can react with other Michael acceptors in an intermolecular fashion, thereby resulting in the formation of homo- or heterodimeric olefins. This "Michael umpolung" should become a valuable method for the formation of densely functionalized olefins.