1334484-98-8Relevant articles and documents
Biomimetic total synthesis of angelicoin A and B via a palladium-catalyzed decarboxylative prenylation-aromatization sequence
Anderson, Katie,Calo, Frederick,Pfaffeneder, Toni,White, Andrew J. P.,Barrett, Anthony G. M.
, p. 5748 - 5750 (2012/01/06)
Five-step total syntheses of angelicoin A and B from 2,2,6-trimethyl-4- dioxinone are reported using late stage biomimetic aromatization reactions via diketo-dioxinones as intermediates. In addition, with angelicoin A, this aromatization was coupled with a palladium-catalyzed decarboxylative prenylation in a one-pot sequence as the key step.