1334496-22-8

Basic information

• Product Name: 2-((1S,2R,3S)-3',4'-dichloro-5-methyl-2-nitro-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl)acetaldehyde
• CAS NO: 1334496-22-8
• Molecular Weight: 328.195
• Mol File: 1334496-22-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-((1S,2R,3S)-3',4'-dichloro-5-methyl-2-nitro-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl)acetaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((1S,2R,3S)-3',4'-dichloro-5-methyl-2-nitro-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl)acetaldehyde(1334496-22-8)
• EPA Substance Registry System: 2-((1S,2R,3S)-3',4'-dichloro-5-methyl-2-nitro-1,2,3,6-tetrahydro-[1,1'-biphenyl]-3-yl)acetaldehyde(1334496-22-8)

Safety Data

• Hazardous Substances Data: 1334496-22-8(Hazardous Substances Data)

Upstream product

• 17424-21-4 5-methyl-hexadien-trans-2,4-al 
• 37630-23-2 1,2-dichloro-4-(2-nitrovinyl)benzene 

Relevant articles and documents

Exo-selective asymmetric Diels-Alder reaction of 2,4-dienals and nitroalkenes by trienamine catalysis

Raising the HOMO: 2,4-Dienals can react with nitroalkenes in trienamine-catalyzed asymmetric Diels-Alder reactions (see scheme). Crucial for the success is raising the HOMO energy of the diene through the introduction of appropriate substituents. The reaction exhibits unusually high enantioselectivity and exo selectivity; endo addition is possibly disfavored because of the electrostatic repulsion shown in the scheme. Copyright