1334511-59-9

Basic information

• Product Name: N-(9-fluorenylmethoxycarbonyl)-valyl-N-ethyl-S-triphenylmethyl-L-cysteine
• Synonyms: N-(9-fluorenylmethoxycarbonyl)-valyl-N-ethyl-S-triphenylmethyl-L-cysteine
• CAS NO: 1334511-59-9
• Molecular Weight: 712.91
• Mol File: 1334511-59-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(9-fluorenylmethoxycarbonyl)-valyl-N-ethyl-S-triphenylmethyl-L-cysteine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(9-fluorenylmethoxycarbonyl)-valyl-N-ethyl-S-triphenylmethyl-L-cysteine(1334511-59-9)
• EPA Substance Registry System: N-(9-fluorenylmethoxycarbonyl)-valyl-N-ethyl-S-triphenylmethyl-L-cysteine(1334511-59-9)

Safety Data

• Hazardous Substances Data: 1334511-59-9(Hazardous Substances Data)

Upstream product

• 86060-87-9 Fmoc-Val-OPfp 

Relevant articles and documents

Efficient preparation of Fmoc-aminoacyl-N-ethylcysteine unit, a key device for the synthesis of peptide thioesters

The synthesis of Fmoc-aminoacyl-N-ethyl-S-triphenylmethylcysteine, an N- to S-acyl migratory device for the preparation of peptide thioesters by Fmoc-SPPS (solid-phase peptide synthesis) is described. Condensation of Fmoc-aminoacyl pentafluorophenyl ester and N-ethyl-S-triphenylmethylcysteine was efficiently performed in the presence of HOOBt (3-hydroxy-3,4-dihydro-4-oxo-1,2,3- benzotriazine) in DMF. A small amount of diastereomer yielded during the reaction was easily separated by HPLC purification and the highly pure devices were obtained for most of the proteinogenic amino acids.