1335133-80-6

Basic information

• Product Name: 3-(benzylsulfonyl)-1-phenylpyrrolidine-2,5-dione
• Synonyms: 3-(benzylsulfonyl)-1-phenylpyrrolidine-2,5-dione
• CAS NO: 1335133-80-6
• Molecular Weight: 329.376
• Mol File: 1335133-80-6.mol

Chemical Properties

• CAS DataBase Reference: 3-(benzylsulfonyl)-1-phenylpyrrolidine-2,5-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(benzylsulfonyl)-1-phenylpyrrolidine-2,5-dione(1335133-80-6)
• EPA Substance Registry System: 3-(benzylsulfonyl)-1-phenylpyrrolidine-2,5-dione(1335133-80-6)

Safety Data

• Hazardous Substances Data: 1335133-80-6(Hazardous Substances Data)

Upstream product

• 1939-99-7 benzenesulfonyl chloride 
• 100-39-0 benzyl bromide 
• 941-69-5 N-phenyl-maleimide 
• 100-53-8 phenylmethanethiol 
• 95498-43-4 3-(benzylthio)-1-phenylpyrrolidine-2,5-dione 

Downstream Products

• 73082-85-6 1-[1-(benzylsulfonyl)allyl]benzene 
• 87156-76-1 (E)-(3-(benzylsulfonyl)prop-1-en-1-yl)benzene 
• 73082-82-3 1-((but-3-en-2-ylsulfonyl)methyl)benzene 
• 1335134-01-4 1-{[2-(benzylsulfonyl)but-3-enyloxy]methyl}benzene 
• 1335134-09-2 1-{[(E)-4-(benzylsulfonyl)but-2-enyloxy]methyl}benzene 
• 1335134-00-3 1-[(4-methylpent-1-en-3-ylsulfonyl)methyl]benzene 
• 1335134-08-1 1-{[(E)-4-methylpent-2-enylsulfonyl]methyl}benzene 
• 1335134-02-5 1-[(E)-3-(benzylsulfonyl)but-1-enyl]benzene 
• 1335134-10-5 {[(E)-1-phenylbut-2-enylsulfonyl]methyl}benzene 
• 1335134-04-7 1-{[(E)-pent-3-en-2-ylsulfonyl]methyl}benzene 
• 1335133-98-6 1-[(hept-1-en-3-ylsulfonyl)methyl]benzene 
• 1335134-07-0 1-{[(E)-hept-2-enylsulfonyl]methyl}benzene 
• 1335133-99-7 C₁₂H₁₄O₄S 
• 289506-11-2 (((3-methylbut-2-en-1-yl)sulfonyl)methyl)benzene 

Relevant articles and documents

Photocatalytic Radical Alkylation of Electrophilic Olefins by Benzylic and Alkylic Zinc-Sulfinates

Alkyl radicals are obtained by photocatalytic oxidation of readily prepared or commercially available zinc sulfinates. The convenient benzylation and alkylation of a variety of electron-poor olefins triggered by the iridium(III) complex 6 Ir[dF(CF3)ppy]2(dtbbpy)PF6 as photocatalyst is described. Moreover, it is shown that zinc sulfinates can be used for facile nonradical sulfonylation reactions with highly electrophilic Michael acceptors.

α-Sulfonyl succinimides: Versatile sulfinate donors in Fe-catalyzed, salt-free, neutral allylic substitution

Allyl sulfones are versatile intermediates in organic chemistry. The presence of two distinct functional groups sets the stage for a plethora of subsequent transformations. However, despite these advantages the preparation of regioisomerically enriched sulfones is not easy. The use of sulfinate salts as nucleophiles in substitutions is frequently accompanied by side reactions such as π-bond migration, β-elimination, and so on. Herein we present a preparatively simple way to synthesize a variety of different aryl or alkyl allyl sulfones starting from readily accessible allylic carbonates. By employing aryl or alkyl α-sulfonyl succinimides as sulfinate synthons, mild and regioselective ipso substitution of diverse allylic carbonates was realized.