13353-49-6

Basic information

• Product Name: 1,2-Dihydrocyclobuta[b]quinoline
• Synonyms: 1,2-Dihydrocyclobuta[b]quinoline
• CAS NO: 13353-49-6
• Molecular Formula: C11H9N
• Molecular Weight: 155.2
• Mol File: 13353-49-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,2-Dihydrocyclobuta[b]quinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Dihydrocyclobuta[b]quinoline(13353-49-6)
• EPA Substance Registry System: 1,2-Dihydrocyclobuta[b]quinoline(13353-49-6)

Safety Data

• Hazardous Substances Data: 13353-49-6(Hazardous Substances Data)

Upstream product

• 111881-64-2 (2-hydroxymethyl-phenyl)-carbamic acid benzyl ester 
• 5344-90-1 2-Aminobenzyl alcohol 

Relevant articles and documents

Synthesis of 1,2-Dihydrocyclobuta[b]quinoline Derivatives from Isocyanophenyl-Substituted Methylenecyclopropanes

A new protocol to synthesize 1,2-dihydrocyclobuta[b]quinoline derivatives from isocyanophenyl-substituted methylenecyclopropanes via a formal insertion of isocyanide carbon into a C?C bond has been developed. The reaction proceeds smoothly in the presence of silver carbonate (5 mol%) upon heating in a highly atom economic manner and exhibits broad substrate scope, giving the desired products in moderate to excellent yields. Furthermore, several transformations of the obtained products have been also demonstrated. (Figure presented.).