133546-75-5

Upstream product

• 79026-61-2 (R)-3-benzyloxy-2-methylpropanal 
• 56850-58-9 methyl (2R)-3-(benzyloxy)-2-methylpropanoate 
• 63930-46-1 (S)-3-benzyloxy-2-methylpropan-1-ol 
• 100-39-0 benzyl bromide 

Downstream Products

• 1448544-38-4 (1S)-1-[(1R)-2-(benzyloxy)-1-methylethyl]prop-2-en-1-yl-(2S)-2-methylbut-3-enoate 
• 1448544-39-5 (1S)-1-[(1R)-2-(benzyloxy)-1-methylethyl]prop-2-en-1-yl-(2E)-2-methylbut-2-enoate 
• 1448544-40-8 (3S,6S)-6-[(1R)-2-(benzyloxy)-1-methylethyl]-3-methyl-3,6-dihydro-2H-pyran-2-one 
• 1448544-43-1 C₂₄H₄₂O₂SSi 
• 1448544-46-4 (2S,3S,6S)-6-[(1R)-2-triisopropylsilyloxy-1-methylethyl]-3-methyltetrahydro-2H-pyran-2-yl 
• 191151-74-3 (3S,4R)-5-(benzyloxy)-4-methylpent-1-en-3-ol 

Relevant academic research and scientific papers

Synthesis of a C1-C11 fragment of Zincophorin using planar chiral, neutral π-allyl iron complexes

A key step in the synthesis of a C1-C11 fragment of the ionophore antibiotic Zincophorin involves the addition of an α-alkoxyalkylcopper(i) reagent to a planar chiral, neutral π-allyl iron complex. The key allylic alkylation reaction is highly regio- and

Diastereoselectivity Enhancement in Vinylcuprate Addition to β-Alkoxyaldehydes Via a Vinylsilane.

The presence of a removable 1-(trimethylsilyl) residue greatly increases the chelation-controlled diastereoselectivity in alkenylcuprate additions to chiral β-alkoxyaldehydes.Several methods for protiodesilylation of the resultant allylic alcohols 2b (R=Me3SiCH2CH2OCH2-, PhCH2OCH2-, and PhCH2-)> are compared.