133586-43-3Relevant articles and documents
α,β-UNSATURATED FLUORINE-CONTAINING THIOCYANATES
Popkova, V. Ya.,Mysov, E. I.,Galakhov, M. V.,Osmanov, V. K.,German, L. S.
, p. 2599 - 2602 (1990)
A new method has been developed for the synthesis of perfluorinated α,β-unsaturated thiocyanates by the reaction of the corresponding sulfenyl chlorides with KCN in water.The thiocyanate form of perfluoro-2-methyl-2-pentene-3-thiocyanate was isomerized to the isothiocyanate form.This rearrangement is initiated by both fluoride and thiocyanate anions.
Reaction of Perfluoro(1-ethyl-2-methyl-1-propenyl) Isothiocyanate with Thiourea
Furin,Zhuzhgov
, p. 1606 - 1609 (2007/10/03)
Perfluoro(1-ethyl-2-methyl-1-propenyl) isocyanate reacts with thiourea in the presence of triethylamine to give a mixture of 4-tetrafluroethylidene-5,5-di(trifluoromethyl)-1,3-thiazolidine-2-thione, perfluoro-[bis(4-ethylidene-5,5-dimethyl-4,5-dihydro-1,3-thiazol-2-yl)] sulfide and perfluoro[bis(4-ethylidene-5,5-dimethyl-4,5-dihydro-1,3-thiazol-2-yl)] disulfide.
Reactions of Some Internal Perfluoroolefins with Sodium and Potassium Thiocyanates
Furin, G. G.
, p. 465 - 468 (2007/10/03)
Reactions of perfluoro-2-methyl-2-pentene, perfluoro-3-isopropyl-4-methyl-2-pentene, and perfluoro-1-ethyl-cyclohexene with potassium and sodium thiocyanates result in substitution of the fluorine atom at the double bond.Reactions of perfluoro-2-methyl-3-