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Product FOB Price Min.Order Supply Ability Supplier
Potassium thiocyanate
Cas No: 333-20-0
No Data 1 Gram Metric Ton/Day Hangzhou Dayangchem Co., Ltd. Contact Supplier
Potassium thiocyanate
Cas No: 333-20-0
No Data 5 Metric Ton 5000 Metric Ton/Year SJZ Chenghui Chemical Co., Ltd. Contact Supplier
Potassium Thiocyanate
Cas No: 333-20-0
USD $ 3.0-4.0 / Kilogram 100 Kilogram 50 Metric Ton/Day ORCHID CHEMICAL SUPPLIES LTD Contact Supplier
potassium thiocyanate
Cas No: 333-20-0
USD $ 1100.0-1100.0 / Gram 1000 Gram 10 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier
High purity Various Specifications Potassium thiocyanate CAS:333-20-0
Cas No: 333-20-0
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Potassium thiocyanate, 98%
Cas No: 333-20-0
No Data 1 Kilogram 1 Metric Ton/Week Henan Allgreen Chemical Co.,Ltd Contact Supplier
High quality Potassium Thiocyanate supplier in China
Cas No: 333-20-0
No Data No Data No Data Simagchem Corporation Contact Supplier
Potassium thiocyanate
Cas No: 333-20-0
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Potassium Thiocyanate
Cas No: 333-20-0
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 2500 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
333-20-0 CKNS Potassium thiocyanate
Cas No: 333-20-0
No Data 5 Gram 1 Kilogram/Day HENAN SUNLAKE ENTERPRISE CORPORATION Contact Supplier

333-20-0 Usage

Chemical Properties

Potassium thiocyanate, KSCN,also known as potassium sulfocyanate and potassium rhodanide, is a colorless deliquescent crystalline solid that melts at 173°C (343 OF) and decomposes at 500°C(932 OF). Soluble in water and alcohol,it has no odor and a saline taste.Potassium thiocyanate is used in printing and dyeing textiles, freezing mixtures, manufacturing chemicals, photography and medicine.

Chemical properties

It is colorless monoclinic crystal. It is soluble in water, and it can cool because of the absorption of heat. It is also soluble in alcohol and acetone.
The above information is edited by the chemicalbook of Wang Xiaodong.

Uses

It can be used in electroplating industry for stripping agent, it can also be used refrigerant. It can also be used in the dye industry, photographic industry, pesticides and steel analysis.

Uses

manufacture of artificial mustard oil; printing and dyeing textiles; in photography as intensifier; in analytical chemistry. The sodium salt now is replacing it for most of these uses.

Uses

Analysis of siliver ion; indirect determination of chloride, bromide, and iodide.

Reference quality standards


Solubility in water (g / 100ml)

The grams which dissolved in per 100 ml of water at different temperatures (℃) :
177g/0 ℃; 198g/10 ℃; 224g/20 ℃; 255g/30 ℃; 289g/40 ℃
372g/60 ℃; 492g/80 ℃; 571g/90 ℃; 675g/100 ℃

Outline

Potassium thiocyanate, molecular formula is KSCN, it is also known as KSCN, English is Potassium Thiocyanate, it is colorless monoclinic crystal. The relative density is 1.886. Melting point is about 172.3 ℃. It is soluble in water and it can cool because of the absorption of heat, it is also soluble in alcohol (ethanol) and acetone. Crystalline hemihydrate (KSCN.0.5H2O) can be obtained at low temperature, it is steady at-29-6.8℃, and it can turn blue when be broiled at about 430℃, but it then re-becomes colorless when be colded. When be heated to 500℃, it can decompose. The blood red ferric thiocyanate complex ion FeSCN2 + (iron thiocyanate) can generate in case of Fe3 + (ferric), which is the sensitive method to test the Fe3 + ion, the method can eliminate the influence of all other known metal ions. And it can not react with ferrous salts. It is hygroscopic, and it should be sealed. It has low toxicity. But potassium cyanate is highly toxic substances, the country has limited its production.

Production method

The mothod of ammonium thiocyanate transformation which is the pressurized synthesis reaction of carbon disulfide and ammonia can generate ammonium thiocyanate and the by-product is ammonium hydrosulfide, and then by desulfurization, ammonium hydrosulfide can evaporate and remove which is decomposed into hydrogen sulfide, when potassium carbonate solution is added into the temperature of 105℃ liquid, it can generates potassium thiocyanate. The reaction process will produce large amount of carbon dioxide and ammonia. Ammonia is recyclable, the reaction solution is filtered to remove insoluble material, and then reduction vaporization is proceeded, and then cooling and crystallization, centrifugal separation is proceeded to obtain industrial potassium thiocyanate.
CS2 + 3NH3 → NH4SCN + NH4HS
NH4HS → NH3 ↑ + H2S ↑
2NH4SCN + K2CO3 → 2KSCN + (NH4) 2CO3
(NH4) 2CO3 → 2NH3 ↑ + CO2 ↑ + H2O

Purification Methods

Crystallise it from H2O if much chloride ion is present in the salt, otherwise from EtOH or MeOH (optionally by addition of Et2O). Filter off on a Büchner funnel without paper, and dry it in a desiccator at room temperature before heating for 1hour at 150o, with a final 10-20minutes at 200o to remove the last traces of solvent [Kolthoff & Lingane J Am Chem Soc 57 126 1935]. Store it in the dark.

Definition

ChEBI: A potassium salt which is the monopotassium salt of thiocyanic acid.
InChI:InChI=1/CNS.K/c2-1-3;/q-1;+1

333-20-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (P3011)  Potassiumthiocyanate  ReagentPlus®, ≥99.0% 333-20-0 P3011-1KG 1,377.09CNY Detail
Sigma-Aldrich (P3011)  Potassiumthiocyanate  ReagentPlus®, ≥99.0% 333-20-0 P3011-500G 1,103.31CNY Detail
Sigma-Aldrich (P3011)  Potassiumthiocyanate  ReagentPlus®, ≥99.0% 333-20-0 P3011-100G 398.97CNY Detail
Honeywell (60520)  Potassiumthiocyanate  purum p.a., ≥98.0% (AT) 333-20-0 60520-2.5KG 3,720.60CNY Detail
Honeywell (60520)  Potassiumthiocyanate  purum p.a., ≥98.0% (AT) 333-20-0 60520-1KG 1,333.80CNY Detail
Honeywell (60520)  Potassiumthiocyanate  purum p.a., ≥98.0% (AT) 333-20-0 60520-250G 455.13CNY Detail
Sigma-Aldrich (207799)  Potassiumthiocyanate  ACS reagent, ≥99.0% 333-20-0 207799-2.5KG 4,483.44CNY Detail
Sigma-Aldrich (207799)  Potassiumthiocyanate  ACS reagent, ≥99.0% 333-20-0 207799-500G 1,537.38CNY Detail
Sigma-Aldrich (207799)  Potassiumthiocyanate  ACS reagent, ≥99.0% 333-20-0 207799-100G 618.93CNY Detail
Sigma-Aldrich (31272)  Potassiumthiocyanate  puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99% 333-20-0 31272-1KG 1,749.15CNY Detail
Fluka (35194)  Potassiumthiocyanatesolution  volumetric, 0.1 M KSCN 333-20-0 35194-1L 476.19CNY Detail
Fluka (38140)  Potassium thiocyanate concentrate  for 1L standard solution, 0.1 M KSCN 333-20-0 38140-6X1EA 1,884.87CNY Detail

333-20-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name potassium thiocyanate

1.2 Other means of identification

Product number -
Other names Potassium sulfocyanate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:333-20-0 SDS

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