133594-52-2Relevant academic research and scientific papers
Synthesis and reactivity of ynhydrazines
Croutte, H. de,Janousek, Z.,Pongo, L.,Merenyi, R.,Viehe, H. G.
, p. 745 - 750 (2007/10/02)
The first examples of ynhydrazines are described of which the 1-trimethylhydrazino-2-phenylacetylene 4 is studied in particular.Besides the expected reactivity, analogous but weaker than that of the corresponding ynamine towards phenol, cyanhydric acid, allylic alcohol, benzoic anhydride, benzaldehyde and formaldehyde, this ynhydrazine undergoes smooth retro-ene type fragmentation producing N-methylphenylketenimine above 100 deg C.Another particularity is heterocylization with phosgene producing a pyrazolone derivative through dechloromethylation.Keywords: ynhydrazine / retro-ene reaction / ketenimine / hydrazide
