13360-20-8Relevant articles and documents
Reduction of allylpalladium(II)chloride dimer by formation of allyloxysilanes
Denmark, Scott E.,Smith, Russell C.
, p. 2921 - 2928 (2006)
The reduction of allylpalladium(II)chloride dimer (APC) to a Pd(0) species can be effected by reaction with alkali metal silanolates. The reduction is extremely rapid in the presence of chelating bisphosphine ligands and for a variety of silanolates. Geor
An Efficient Catalyst for the Conversion of Hydrosilanes to Alkoxysilanes
Lorenz, Catrin,Schubert, Ulrich
, p. 1267 - 1270 (2007/10/03)
The copper(I) hydride 6 is an efficient catalyst for the alcoholysis of primary and secondary silanes.The reactions proceed at room temperature within a few hours and give the alkoxysilanes in high yields.Only with bulky alcohols or silanes are longer reaction times and/or increased temperatures required.The presence of air accelarates the reactions and gives rise to higher yields of alkoxysilanes, particularly with bulky alcohols.Diols react with PhRSiH2 (R = Me, Ph) to afford 1,3-dioxo-2-silacycloalkanes and with tertiary silanes to furnish the bissilylated diols.When unsaturated alcohols (2-propen-1-ol or 2-propyn-1-ol) are employed, the double or triple bond is retained. - Keywords: Catalytic silane alcoholysis; Alkoxysilanes
REACTIONS OF ALLYL ALCOHOL WITH TRIORGANOSILANES IN PRESENCE OF ION-EXCHANGERS
Zaslavskaya, T. N.,Reikhsfel'd, V. O.,Filippov, N. A.,Shornik, N. A.
, p. 2001 - 2005 (2007/10/02)
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