133609-19-5

Basic information

• Product Name: cyclohexanone O-(3-phenylprop-2-enyl)oxime
• Synonyms: cyclohexanone O-(3-phenylprop-2-enyl)oxime
• CAS NO: 133609-19-5
• Molecular Weight: 229.322
• Mol File: 133609-19-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: cyclohexanone O-(3-phenylprop-2-enyl)oxime(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexanone O-(3-phenylprop-2-enyl)oxime(133609-19-5)
• EPA Substance Registry System: cyclohexanone O-(3-phenylprop-2-enyl)oxime(133609-19-5)

Safety Data

• Hazardous Substances Data: 133609-19-5(Hazardous Substances Data)

Upstream product

• 100-64-1 cyclohexanone-oxime 
• 7217-71-2 1-phenyl-2-propenyl acetate 
• 85669-63-2 (E)-cinnamyl diethyl phosphate 

Downstream Products

• 1570-04-3 2-phenyl-5,6,7,8-tetrahydroquinoline 

Relevant articles and documents

Novel synthesis of O-allylated oxime ethers based on allylic substitution with oximes

The palladium or iridium-catalyzed O-allylic substitution of oximes provides a new method for direct preparation of the O-allylated oxime ethers from oximes.

Utility of the iridium complex of the pybox ligand in regio- and enantioselective allylic substitution

(Chemical equation presented) The viability of the iridium complex of pybox as chiral catalyst in allylic substitutions and the enantioselective synthesis of branched products was studied. Among several chiral ligands evaluated, the iridium complex of pybox having a phenyl group catalyzed the reaction with high activity to form the branched amines with good enantioselectivities when hydroxylamine, amine, and aniline were employed as a nucleophile. The allylic substitution with oximes proceeded smoothly to give the branched oxime ethers with good enantioselectivities.