7217-71-2

Basic information

• Product Name: alpha-vinylbenzyl acetate
• Synonyms: alpha-vinylbenzyl acetate;1-Phenyl-2-propene-1-ol acetate;1-Phenyl-2-propenyl acetate;Acetic acid 1-phenylallyl ester;α-Ethenylbenzenemethanol acetate;α-Vinylbenzenemethanol acetate
• CAS NO: 7217-71-2
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.21178
• EINECS: 230-606-2
• Mol File: 7217-71-2.mol
• Article Data: 44

Chemical Properties

• Boiling Point: 111 °C(Press: 16 Torr)
• Appearance: /
• Density: 1.029±0.06 g/cm3(Predicted)
• CAS DataBase Reference: alpha-vinylbenzyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: alpha-vinylbenzyl acetate(7217-71-2)
• EPA Substance Registry System: alpha-vinylbenzyl acetate(7217-71-2)

Safety Data

• Hazardous Substances Data: 7217-71-2(Hazardous Substances Data)

Upstream product

• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 127-08-2 potassium acetate 
• 563-63-3 silver(I) acetate 
• 873-66-5 1-propenylbenzene 
• 64-19-7 acetic acid 
• 300-57-2 allylbenzene 
• 104713-12-4 (R)-1-phenylprop-2-en-1-ol 
• 108-24-7 acetic anhydride 
• 108-05-4 vinyl acetate 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 108-59-8 malonic acid dimethyl ester 
• 108-22-5 Isopropenyl acetate 
• 766-90-5 cis-1-phenyl-1-propylene 
• 21040-45-9 Cinnamyl acetate 

Downstream Products

• 21040-45-9 Cinnamyl acetate 
• 40595-34-4 (E)-trimethyl(3-phenylallyl)silane 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 4957-18-0 1-methoxy-4-(3-methyl-but-2-enyl)benzene 
• 130860-69-4 dimethyl 2-[(E)-cinnamyl]-2-propargylmalonate 
• 40595-35-5 (Z)-1-phenyl-3-(trimethylsilyl)-1-propene 
• 300-57-2 allylbenzene 
• 873-66-5 1-propenylbenzene 
• 74120-63-1 (E)-1,4-diphenyl-1,5-hexadiene 
• 76524-57-7 (E)-4,4-dimethyl-1-phenylhexa-1,5-diene 
• 87802-79-7 Dimethyl methyl(1-phenylprop-2-en-1-yl)malonate 
• 189884-53-5 2-methyl-2-(3-phenyl-2-propenyl)malonic acid dimethyl ester 
• 58463-02-8 (1E,5E)-1,6-diphenyl-1,5-hexadiene 
• 7217-71-2 (R)-(+)-1-acetoxy-1-phenyl-2-propylene 

Relevant articles and documents

Base-Free Dynamic Kinetic Resolution of Secondary Alcohols with a Ruthenium-Lipase Couple

We report the dynamic kinetic resolution (DKR) of various secondary alcohols by the combination of a ruthenium catalyst and an anionic surfactant-activated lipoprotein lipase. The DKR reactions performed under totally base-free conditions at room temperature provided the products of excellent enantiopurities (91-99% ee or greater) in high yields (92-99%). More importantly, the DKR of α-arylallyl alcohols was achieved for the first time with high yields (87-91%).

A Re2O7catalyzed cycloetherification of monoallylic diols

A Re2O7catalyzed cycloetherification of monoallylic diols is described. The reaction features short reaction time, mild reaction conditions and exclusive E selectivity. A wide range of monoallylic alcohols with alkyl or aryl substituents on olefin smoothly undergo ring closure to deliver corresponding oxa-heterocycles. The reaction is also operationally simple and not sensitive to air and moisture.