13361-31-4

Usage

Uses

Isobutyl Cyanoacetate is a useful research chemical.

Chemical Properties

CLEAR COLOURLESS LIQUID

InChI:InChI=1/C7H11NO2/c1-6(2)5-10-7(9)3-4-8/h6H,3,5H2,1-2H3

Upstream product

• 78-83-1 2-methyl-propan-1-ol 
• 372-09-8 cyanoacetic acid 

Downstream Products

• 143270-18-2 2-cyano-5-phenyl-penta-2,4-dienoic acid isobutyl ester 
• 40674-28-0 {(E)-4-[Bis-(2-chloro-ethyl)-amino]-phenylimino}-cyano-acetic acid isobutyl ester 
• 129779-47-1 (1S,2R,4S,5R)-6-Cyano-2-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-4-[(4-methoxy-phenyl)-diphenyl-methoxymethyl]-3-oxa-bicyclo[3.1.0]hexane-6-carboxylic acid isobutyl ester 
• 131534-55-9 Bromo-cyano-acetic acid isobutyl ester 
• 803699-16-3 isobutyl 3-(4-aminophenyl)-2-cyanoacrylate 
• 88107-27-1 isobutyl 3-(benzylmethylamino)-2-cyano-2-propenoate 
• 1356255-39-4 7-cyano-7-(isobutoxycarbonyl)-1,4-benzoquinonemethide 
• 1356255-73-6 4-[1'-cyano-1'-(isobutoxycarbonyl)methylene]cyclohexanone 
• 1419401-89-0 2-methylpropyl (2Z)-cyano{3-[(3- methoxypropyl)amino]cyclohex-2- en-1-ylidene}ethanoate 
• 1419401-71-0 C₁₆H₂₄N₂O₃ 
• 1419401-78-7 2-methylpropyl 2-cyano{3-[(3-methoxypropyl)amino]cyclohex-2-en-1-ylidene}ethanoate 
• 78-83-1 2-methyl-propan-1-ol 

Relevant academic research and scientific papers

Ligand-dependent mechanistic dichotomy in iron-catalyzed allylic substitutions: σ-allyl versus π-allyl mechanism

(Chemical Equation Presented) Iron at the crossroads: A remarkable mechanistic dichotomy in iron-catalyzed allylic substition increases not only the scope of regioselective allylic alkylation but could also herald the development of asymmetric allylic substitution (see Scheme, MTBE = methyl tert-butyl ether). Depending on the ligand used, either a σ-or a π-allyl mechanism is observed.

Preparation of alkyl cyanoacetates

A process for the preparation of C4 -C10 alkyl cyanoacetates by the reaction of cyanoacetic acid with C4 -C10 alkanols at a temperature of from 35° to 150° C. and under a pressure of from 70 to 1013 mbar, in the presence of catalytic amounts of acid, while a C4 -C10 alkanol/water azeotrope is separated during the reaction.