13362-39-5Relevant academic research and scientific papers
New preparative procedure for the synthesis of chloroalkyl sulfides
Russavskaya,Korchevin,Alekminskaya,Sukhomazova,Levanova,Deryagina
, p. 1445 - 1448 (2002)
Reaction of thiols with dihaloalkanes in the system hydrazine hydrate-base leads to alkyl(chloroalkyl) sulfides with different positions of the chlorine atom with respect to sulfur. The developed one-step procedure for the synthesis of such unsymmetrical sulfides is most suitable for arenethiols and alkanethiols having a long polymethylene chain. The reaction mechanism is discussed.
