13362-71-5Relevant academic research and scientific papers
CO-OLIGOMERISATION DE BUTADIENE ET D'HETERODIENES AZOTES CATALYSEE PAR LE NICKEL CONTROLE DE LA SELECTIVITE
Brun, P.,Tenaglia, A,Waegell, B
, p. 5019 - 5030 (2007/10/02)
Nickel (0) catalysed co-oligomerization of butadiene with heterodienes and hetero-olefins is described.It is shown how the selectivity of these reactions can be controlled by the position of the heteroatom in the heteropartner and also by the nature of th
The Photolysis of p-Tosylhydrazones of Aryl and α,β-Unsaturated Carbonyl Compounds
Bellesia, Franco,Grandi, Romano,Pagnoni, Ugo M.,Trave, Roberto
, p. 1301 - 1309 (2007/10/02)
The ultraviolet irradiation of p-tosylhydrazones of aryl and α,β-unsaturated carbonyl compounds yields azines and sulphones and exhibits a strong solvent effect.Styryl substrates afford α,β-unsaturated sulphones, the shift of the olefinic double bond probably arising through an intermediate azoderivative.The p-tosylhydrazone of benzylideneacetone is to a great extent transformed to the cis isomer.
