133620-57-2Relevant academic research and scientific papers
A New Type of Reductive Cleavage of Disulfide in Quadruply ortho-Substituted Diphenyl Disulfide by Neighboring Thiolate Anion
Fujihara, Hisashi,Chiu, Jer-Jye,Furukawa, Naomichi
, p. 699 - 701 (2007/10/02)
The reaction of bisdisulfide with thiourea or sodium sulfide showed an unusual reductive cleavage of disulfide linkage with elimination of bromine by neighboring-group participation of the generated thiolate anion.Its reaction gave the structurally intriguing thiols which indicated the facile anodic oxidation.
