133857-67-7Relevant academic research and scientific papers
Potassium tert -Butoxide Mediated Arylation of 2-Substituted Malononitriles Using Diaryliodonium Salts
Han, Jianwei,Qian, Xiaofei,Xu, Bowen,Wang, Limin
supporting information, p. 2139 - 2142 (2017/09/26)
Direct arylation of 2-substituted malononitriles using diaryliodonium salts without involving transition-metal catalysts was developed. By using potassium tert -butoxide as a promoter, the desired 2-substituated α-arylmalononitriles derivatives were synthesized in good to excellent yields of 55-96%. This synthetic method provided an efficient way to prepare a variety of 2-substituted arylmalononitriles which were useful in agrochemicals.
The C-Arylation of α-Cyano Esters and Malononitriles by Aryllead(IV) Triacetates
Kozyrod, Robert P.,Morgan, Jacqueline,Pinhey, John T.
, p. 369 - 376 (2007/10/02)
The arylation of soft carbon nucleophiles by aryllead(IV) triacetates has been extended to α-cyano esters and malononitriles.Arylation did not occur with the parent compounds, ethyl cyanoacetate and malononitrile, but in both series monosubstituted compou
